周航, 肖锦华, 曾敏, 等. 2种无机洗脱剂对矿区污染土壤中铅、镉的洗脱研究[J]. 生态与农村环境学报, 2010, 26(3): 241-245.
    引用本文: 周航, 肖锦华, 曾敏, 等. 2种无机洗脱剂对矿区污染土壤中铅、镉的洗脱研究[J]. 生态与农村环境学报, 2010, 26(3): 241-245.
    ZHOU Hang, XIAO Jin-Hua, ZENG Min, et al. Effects of Two Inorganic Eluents on Removal of Pb and Cd From Mining-Contaminated Soils[J]. Journal of Ecology and Rural Environment, 2010, 26(3): 241-245.
    Citation: ZHOU Hang, XIAO Jin-Hua, ZENG Min, et al. Effects of Two Inorganic Eluents on Removal of Pb and Cd From Mining-Contaminated Soils[J]. Journal of Ecology and Rural Environment, 2010, 26(3): 241-245.

    2种无机洗脱剂对矿区污染土壤中铅、镉的洗脱研究

    Effects of Two Inorganic Eluents on Removal of Pb and Cd From Mining-Contaminated Soils

    • 摘要: 选用HCl和CaCl22种无机洗脱剂对矿区重金属污染土壤进行化学洗脱试验,分析比较了2种洗脱剂对土壤中Pb、Cd的洗脱效果,并探讨了洗脱剂浓度、洗脱时间、温度、固液比、洗脱次数对土壤中Pb、Cd洗脱效果的影响。结果表明,对于土壤中Pb的洗脱,HCl的效果优于CaCl2,其洗脱率分别为26.0%~68.2%和14.6%~48.7%;而对于土壤中Cd的洗脱,CaCl2优于HCl,其洗脱率分别为30.7%~54.6%和24.2%~42.6%。在各影响因素中,洗脱剂浓度对土壤中Pb的洗脱有显著影响,而洗脱次数对土壤中Cd的洗脱有显著影响,其他因素对Pb、Cd的洗脱均无显著影响。洗脱土壤中Pb的最佳操作条件为:HCl 200 mmol.L-1、时间240 min、温度20℃、m(固)∶V(液)=1∶15、洗脱2次;洗脱土壤中Cd的最佳操作条件为:CaCl2 50 mmol.L-1、时间240 min、温度35℃、m(固)∶V(液)=1∶20、洗脱4次。

       

      Abstract: Two inorganic eluents,HCl and CaCl2,were tested in an experiment to elute Pb and Cd from heavy metal contaminated soil in a mining area for comparison of their efficiencies and for investigation of factors, such as eluent concentration, timing, temperature, solid-liquid ratio and frequency of elution, affecting elution efficiency. It was found that HCl was better than CaCl2 in removing Pb and their Pb removal rate was 26.0%-68.2% and 14.6%-48.7%,respectively,but CaCl2 was better than HCl in removing Cd and their Cd removal rate was 30.7%-54.6% and 24.2%-42.6%, respectively. Among the factors studied,eluent concentration had a significant effect on Pb removal rate,while elution frequency had on Cd removal rate. No significant impact was observed from other factors.The optimal elution conditions for Pb from soil are: HCl 200 mmol·L-1 in concentration; 240 min in duration; 20 ℃ in temperature; 1∶15 in m (solid)∶ V( liquid) ratio and 2 in frequency; whereas the conditions for Cd from soil are: CaCl2 50 mmol·L-1 in concentration; 240 min in duration; 35 ℃ in temperature; 1∶20 in m (solid)∶ V(liquid) ratio and 4 in frequency.

       

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