生态与农村环境学报 ›› 2011, Vol. 27 ›› Issue (2): 109-112.doi:

• 研究简报 • 上一篇    

红色黏土对磷的吸附性能及其机理初探

王伟, 杭小帅, 张毅敏, 依艳丽   

  1. 沈阳农业大学土地与环境学院
  • 收稿日期:2010-11-05 出版日期:2011-03-25 发布日期:2011-04-22
  • 通讯作者: 依艳丽 沈阳农业大学土地与环境学院 E-mail:yiyanli@126.com
  • 作者简介:王伟(1985—),男,辽宁葫芦岛人,硕士生,主要从事环境污染治理与修复研究。E-mail: wangwei316@163.com
  • 基金资助:

    中央级公益性科研院所基本科研业务专项;国家水体污染与治理科技重大专项(2008ZX07101-007)

Phosphorus Adsorption of Red Clay and Its Mechanism

WANG  Wei, HANG  Xiao-Shuai, ZHANG  Yi-Min, YI  Yan-Li   

  1. College of Land and Environment , Shenyang Agriculture University
  • Received:2010-11-05 Online:2011-03-25 Published:2011-04-22
  • Contact: YI Yan-Li College of Land and Environment , Shenyang Agriculture University E-mail:yiyanli@126.com

摘要: 研究了采自江西鹰潭和江苏宜兴2地荒地亚层(20 ~ 40 cm)11种红色黏土的理化性质,比较了其对2种不同质量浓度(35和50 mg•L-1)磷酸二氢钾溶液中磷的吸附性能。结果表明,11种红色黏土对35和50 mg•L-1磷标准溶液的磷吸附量分别为0.52 ~ 0.86和0.52 ~ 1.18 mg•L-1,其中采自江苏的S9土样对2种浓度磷标准溶液的磷去除速率均达90%以上;红色黏土中的铁、铝氧化物是除磷的主要控制因素,溶液中的磷主要与红色黏土中铁、铝氧化物相结合形成难溶性Fe-P和Al-P,土壤氧化铝含量与除磷效果显著正相关。可以通过向红色黏土及其他吸附剂中加入适量的铁、铝氧化物以提高对磷的吸附性能。

关键词: 红色粘土, 磷, 吸附, 水体

Abstract: Physical and chemical properties of 11 different types of red clays collected from the sub-layer (20 – 40 cm) of wastelands in Yingtan of Jiangxi and Yixing of Jiangsu were analyzed and their performances of phosphorus adsorption in 2 solutions different in concentration (35 and 50 mg•L-1) were compared. Results show that the phosphorus adsorption capacities of the samples in the two solutions varied in the range of 0.52 – 0.86 and 0.52 -1.18 mg•L-1, separately. Of the samples, S9 which was collected from Jiangsu demonstrated the highest P removal rate, being over 90% in both solutions. It was also found that iron and aluminum oxides in the red clays were the dominant controlling factors. They combined most of the phosphorus in the solutions, forming insoluble Fe-P and Al-P. the content of aluminum oxides was significantly and positively related to phosphorus removal rate. Therefore, it is advisable to add a proper amount of iron and aluminum oxides into red clay or some other adsorbents to improve their phosphorus adsorption capacity.

Key words: red clay, phosphorus, adsorption, water body