水稻秸秆生物炭对异丙甲草胺的吸附和缓释作用

doi:10.11934/j.issn.1673-4831.2016.01.026

Abstract

Abstract:

Aiming at controlling herbicide pollution of the environment, biochars were prepared out of rice straw through oxygen-limited pyrolysis at low temperatures(200 and 350℃), and their effects of adsorbing and slow-releasing herbicide metolachlor were investigated. Results show that the biochar prepared at temperature of 350℃(D350) was 23.2 m²·g^-1 in specific surface area and hence much higher than rice straw in metolachlor sorption capacity, and close to the biochar prepared at temperature of 200℃(D200). But, biochar D350 showed a higher surface adsorption capacity to metolachlor and a higher desorption hysteresis index(5.35) than D200 did(2.07), indicating that granular preparation of biochar can be used as sustained releaser of metolachlor, with parameter n_r of its in-water release kinetic model being close to that(0.50) of the Fickian diffusion model, and the time it took to release 50% of adsorbed metolachlor(t₅₀) is positively related to the desorption hysteresis index.

Key words: biomass, sorption, herbicide, sustained release

CLC Number:

GE Chao-chao, GUO Xuan, LI Jian-fa, LÜ Jin-hong, LIU Sen, XU Hai-xia. Effects of Rice-Straw-Derived Biochar on Adsorbing and Slow-Releasing of Metolachlor[J]. Journal of Ecology and Rural Environment, 2016, 32(1): 168-172.

References

[1] 毛懿德,铁柏清,叶长城,等.生物炭对重污染土壤镉形态及油菜吸收镉的影响[J].生态与农村环境学报,2015,31(4):579-582.
[2] ROBERTS K G,GLOY B A,JOSEPH S,et al.Life Cycle Assessment of Biochar Systems:Estimating the Energetic,Economic and Climate Change Potential[J].Environmental Science and Technology,2010,44(2):827-833.
[3] 褚军,薛建辉,金梅娟,等.生物炭对农业面源污染氮、磷流失的影响研究进展[J].生态与农村环境学报,2014,30(4):409-415.
[4] YU X Y,MU C L,GU C,et al.Impact of Woodchip Biochar Amendment on the Sorption and Dissipation of Pesticide Acetamiprid in Agricultural Soils[J].Chemosphere,2011,85(8):1284-1289.
[5] LI J,LI Y,WU M,et al.Effectiveness of Low-Temperature Biochar in Controlling the Release and Leaching of Herbicides in Soil[J].Plant and Soil,2013,370(1/2):333-344.
[6] 李文明,秦兴民,李青阳,等.控制释放技术及其在农药中的应用[J].农药,2014,53(6):394-398.
[7] 吕金红,李建法,王杰,等.复合改性黏土对除草剂2,4-D的控制释放作用研究[J].农药学学报,2010,12(1):73-78.
[8] 刘军利,蒋剑春,黄海涛.木质素CP-GC-MS法裂解行为研究[J].林产化学与工业,2009,29(增刊1):1-6.
[9] 陈宝梁,周丹丹,朱利中,等.生物碳质吸附剂对水中有机污染物的吸附作用及机理[J].中国科学:B辑,2008,38(6):530-537.
[10] 吴志丹,尤志明,江福英,等.不同温度和时间炭化茶树枝生物炭理化特征分析[J].生态与农村环境学报,2015,31(4):583-588.
[11] YU X,PAN L,YING G,et al.Enhanced and Irreversible Sorption of Pesticide Pyrimethanil by Soil Amended With Biochars[J].Journal of Environmental Science,2010,22(4):615-620.
[12] CANTRELL K B,HUNT P G,UCHIMIYA M,et al.Impact of Pyrolysis Temperature and Manure Source on Physicochemical Characteristics of Biochar[J].Bioresource Technology,2012,107:419-428.
[13] WANG X,XING B.Sorption of Organic Contaminants by Biopolymer-Derived Chars[J].Environmental Science and Technology,2007,41(24):8342-8348.
[14] LI J,LI Y,WU Y,et al.A Comparison of Biochars From Lignin,Cellulose and Wood as the Sorbent to an Aromatic Pollutant[J].Journal of Hazardous Materials,2014,280:450-457.
[15] CHEN B,ZHOU D,ZHU L.Transitional Adsorption and Partition of Nonpolar and Polar Aromatic Contaminants by Biochars of Pine Needles With Different Pyrolytic Temperatures[J].Environmental Science and Technology,2008,42(14):5137-5143.
[16] LU J,LI J,LI Y,et al.Use of Rice Straw Biochar Simultaneously as the Sustained Release Carrier of Herbicides and Soil Amendment for Their Reduced Leaching[J].Journal of Agricultural and Food Chemistry,2012,60(26):6463-6470.
[17] RITGER P L,PEPPAS N A.A Simple Equation for Description of Solute Release Ⅰ:Fickian and Anomalous Release From NonSwellable Devices in the Form of Slabs,Spheres,Cylinders or Discs[J].Journal of Controlled Release,1987,5(1):23-36.
[18] DONG H,LI F,LI J,et al.Characterizations of Blend Gels of Carboxymethylated Polysaccharides and Their Use for the Controlled Release of Herbicide[J].Journal of Macromolecular Science A,2012,49(3):235-241.

Effects of Rice-Straw-Derived Biochar on Adsorbing and Slow-Releasing of Metolachlor

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIU Lian, ZHAO Yuan, Matthieu NSENGA KUMWIMBA, WANG Tao. Distribution Characteristics of Vegetation Among Different Ditches in the Hilly Area of Sichuan Basin [J]. Journal of Ecology and Rural Environment, 2019, 35(8): 1020-1026.
[2]	CAO Jun-min, LI Xin, XU De-fu. Study on Capacity of Removal and Adsorption of Fluoride From Groundwater by Bone Biochar [J]. Journal of Ecology and Rural Environment, 2019, 35(8): 1064-1070.
[3]	SHAO Ai-yun, CHENG De-yi, DAI Jing-yu, DU Qi-wen, DU Chao, HUANG Zhao-qin. Characteristics of Cd²⁺ Adsorption From Water by Sulfhydryl Group Modified Rice Hull Biochar [J]. Journal of Ecology and Rural Environment, 2019, 35(8): 1071-1079.
[4]	CHANG Hui-qing, ZHU Xiao-hui, ZHENG Cai-jie, JIAO Chang-feng, WANG Qi-zhen, WU Jie. Removal of Low Concentration Phosphate From Aqueous Solution by Particle Anthracite Activated Carbon [J]. Journal of Ecology and Rural Environment, 2019, 35(8): 1058-1063.
[5]	WANG Li, HU Miao, XU Jian-jun. Adsorption Characteristic and Mechanism of Cr⁶⁺ by Shrimp Shell-Derived Biochar [J]. Journal of Ecology and Rural Environment, 2019, 35(8): 1080-1088.
[6]	WANG Heng-xu, LIU Ze-ping, WANG Zhi-gang, XU Wei-hui, GUO Ru-xin. Colonization and Growth Promotion of Three Bacillus Strains in Rice Rhizosphere and Their Survival in Soil [J]. Journal of Ecology and Rural Environment, 2019, 35(7): 892-899.
[7]	MA Jie-chen, WANG Xin-liang, ZHANG Xue-sheng, LI Yu-cheng, ZHENG Liu-gen, WANG Ning. Influence of Pyrolysis Temperature on Characteristics and Zn²⁺ Adsorptive Mechanism of Crayfish Shell Biochars [J]. Journal of Ecology and Rural Environment, 2019, 35(7): 900-908.
[8]	LI Jian-cha, LI Kun, FANG Hai-dong, ZHANG Lei, PAN Zhi-xian, YUE Xue-wen, HE Guang-xiong, DUAN Qi-cai, SHI Liang-tao. Effects of Drip Irrigation Modes on Biomass Allocation, Yield and Water Use Efficiency of Sweet Corn in a Dry Hot Valley [J]. Journal of Ecology and Rural Environment, 2019, 35(7): 947-952.
[9]	GAN Fang-qun, XU Zi-hao, YANG Yi-fan, QIN Pin-zhu, TANG Rong, HANG Xiao-shuai. Phosphate Removal Efficiency of Kaolin in Livestock and Poultry Wastewater and Its Cost-Benefit Analysis [J]. Journal of Ecology and Rural Environment, 2019, 35(6): 795-800.
[10]	WANG Hui, TANG Shan, HAN Shang, LI Min, WU Ji, CHENG Wen-long, WU Ping-ping. The Cadmium Adsorption on Goethite and Humic Acid-Coated Goethite Complexes Under Phosphate Application [J]. Journal of Ecology and Rural Environment, 2019, 35(5): 659-667.
[11]	HE Pu, LIU Hong-yan, WU Long-hua, MU Ting-ting. Accumulation of Copper and Zinc in Grains of Rice and Wheat Cultivars With Contrasting Cadmium Uptake Capacities [J]. Journal of Ecology and Rural Environment, 2019, 35(3): 385-391.
[12]	WEI Jing, GUO Shu-fang, SUN Ben-hua, ZHAI Li-mei, WANG Hong-yuan, LIU Hong-bin, HUA Ling-ling, YANG Bo. Effects of Winter Cover Crops on Soil Nutrients and Microbial Properties of Cinnamon Soil [J]. Journal of Ecology and Rural Environment, 2018, 34(5): 426-432.
[13]	WANG Chan-juan, XIONG Zhi-ting, XU Zhong-rui, LIU Rong-xiang. Isolation, Identification and Adsorption Characteristics of Cd-Resistant Rhizobacteria in a Nonferrous Metal Mine [J]. Journal of Ecology and Rural Environment, 2018, 34(5): 448-455.
[14]	SHEN Lei, JING Yan-de, SUN Xiao-yin, HAO Hao, CAO Yong-qiang. Cd²⁺ Adsorption Characteristics of Animal-Waste-and-Plant-Derived Biochars in Water [J]. Journal of Ecology and Rural Environment, 2018, 34(4): 363-370.
[15]	LI San-shan, WANG Chu-chu, HE Xiao-yun, REN Li-man, GUO Qiong, YANG Liu-yan. Adsorption Characteristics of Low Concentration Nitrate-Nitrogen Onto Modified Macrophytes Biochar [J]. Journal of Ecology and Rural Environment, 2018, 34(4): 356-362.