长三角工业园区土壤中多环芳烃和邻苯二甲酸酯的污染现状及来源解析

doi:10.19741/j.issn.1673-4831.2022.0210

Abstract

Abstract: To assess the status of soil organic pollution in industrial parks, forty-five soil samples were collected from the representative industrial parks in Yangtze River Delta for analyzing soil organic pollution by gas chromatography equipped with a mass spectrometry detector, and their sources were also analyzed by characteristic ratio. There are computer, communication and electronic equipment manufacturing, chemical raw material and product manufacturing, rubber and plastic product manufacturing, automobile manufacturing, and textile and clothing industry in the representative industrial parks. The results show as follows:(1) The soils around the industrial parks were seriously polluted. 23 semi-volatile organic pollutants were detected in soil samples among which the detection rates of polycyclic aromatic hydrocarbons (PAHs) and phthalates (PAEs) were 100% and 75.6%, respectively, and the concentrations were 2.19-15 200.90 μg·kg^-1 and n.d. -4 168.56 μg·kg^-1, respectively. (2) The concentrations of 4-6 rings PAHs in the old industrial parks are higher than those in the new industrial parks. In addition, attention should be paid to the process of soil pollution caused by automobile manufacturing, rubber and plastic manufacturing, computer communication and other manufacturing industries in the industrial parks. (3) The PAHs in soil of industrial parks mainly came from combustion sources. It is necessary to pay more attention to the pollutant discharge in the process of coal and fuel oil burning of enterprises in the parks, and to strengthen the control of PAEs in the production process of rubber and plastic manufacturing and chemical raw materials and chemical products manufacturing.

Key words: Yangtze River Delta, soil, organic pollutants, polycyclic aromatic hydrocarbons, phthalates

CLC Number:

ZHANG Fu-ying, XU Ming, ZHOU Zeng-xing, SUN Lu-lu, LIN Chao-ba, ZHU Xue-zhu. Pollution Status and Sources of Polycyclic Aromatic Hydrocarbons and Phthalates in Soil of Industrial Parks in Yangtze River Delta[J]. Journal of Ecology and Rural Environment, 2023, 39(8): 1077-1085.

References

[1] 环境保护部,国土资源部.全国土壤污染状况调查公报(2014年4月17日)[J].环境教育,2014(6):8-10.
[2] TSIBART A S,GENNADIEV A N.Polycyclic Aromatic Hydrocarbons in Soils:Sources,Behavior,and Indication Significance (a Review)[J].Eurasian Soil Science,2013,46(7):728-741.
[3] LU Z,ZENG F G,XUE N D,et al.Occurrence and Distribution of Polycyclic Aromatic Hydrocarbons in Organo-mineral Particles of Alluvial Sandy Soil Profiles at a Petroleum-contaminated Site[J].Science of the Total Environment,2012,433:50-57.
[4] MANARIOTIS I D,KARAPANAGIOTI H K,CHRYSIKOPOULOS C V.Degradation of PAHs by High Frequency Ultrasound[J].Water Research,2011,45(8):2587-2594.
[5] LEMIEUX C L,LONG A S,LAMBERT I B,et al.Cancer Risk Assessment of Polycyclic Aromatic Hydrocarbon Contaminated Soils Determined Using Bioassay-derived Levels of Benzo[a]Pyrene Equivalents[J].Environmental Science & Technology,2015,49(3):1797-1805.
[6] QI H X,CHEN X L,DU Y E,et al.Cancer Risk Assessment of Soils Contaminated by Polycyclic Aromatic Hydrocarbons in Shanxi,China[J].Ecotoxicology and Environmental Safety,2019,182:109381.
[7] 张雪英,李莲,祝佩茹,等.生物纳米FeS和磁性炭对Klebsiella sp.LZ6降解芘效果的影响[J].南京工业大学学报(自然科学版),2020,42(6):804-813.[ZHANG Xue-ying,LI Lian,ZHU Pei-ru,et al.Effects of Bio-nano FeS and Magnetic Carbon on Pyrene Degradation by Klebsiella Sp.LZ6[J].Journal of Nanjing Tech University (Natural Science Edition),2020,42(6):804-813.]
[8] SINGH I,VAIDYA A N,KUMAR A R.Occurrence,Distribution,Fate and Quantitation of Phthalates in Soils:A Review[J/OL]//[2021-12-22].https://www.tandfonline.com.
[9] EREMINA N,PASCHKE A,MAZLOVA E A,et al.Distribution of Polychlorinated Biphenyls,Phthalic Acid Esters,Polycyclic Aromatic Hydrocarbons and Organochlorine Substances in the Moscow River,Russia[J].Environmental Pollution,2016,210:409-418.
[10] 严青云,杨耀帅,罗海鲲,等.典型塑料生产加工地块土壤邻苯二甲酸酯及多环芳烃污染特征和健康风险[J].农业环境科学学报,2022,41(2):357-366.[YAN Qing-yun,YANG Yao-shuai,LUO Hai-kun,et al.Pollution Characteristics and Health Assessment of Phthalate Esters and Polycyclic Aromatic Hydrocarbon in Soils of Plastic-producing Site[J].Journal of Agro-environment Science,2022,41(2):357-366.]
[11] GARCIA J M,ROBERTSON M L.The Future of Plastics Recycling[J].Science,2017,358(6365):870-872.
[12] SUN J T,PAN L L,TSANG D C W,et al.Organic Contamination and Remediation in the Agricultural Soils of China:A Critical Review[J].Science of the Total Environment,2018,615:724-740.
[13] 冯嫣,吕永龙,焦文涛,等.北京市某废弃焦化厂不同车间土壤中多环芳烃(PAHs)的分布特征及风险评价[J].生态毒理学报,2009,4(3):399-407.[FENG Yan,LÜ Yong-long,JIAO Wen-tao,et al.Distribution and Risk of Polycyclic Aromatic Hydrocarbons in Soils from Different Workshops of an Abandoned Coking Factory in Beijing[J].Asian Journal of Ecotoxicology,2009,4(3):399-407.]
[14] JIAO H H,WANG Q,ZHAO N N,et al.Distributions and Sources of Polycyclic Aromatic Hydrocarbons (PAHs) in Soils around a Chemical Plant in Shanxi,China[J].International Journal of Environmental Research and Public Health,2017,14(10):1198.
[15] 杨帆,罗红雪,钟艳霞,等.宁东能源化工基地核心区表层土壤中多环芳烃的空间分布特征、源解析及风险评价[J].环境科学,2021,42(5):2490-2501.[YANG Fan,LUO Hong-xue,ZHONG Yan-xia,et al.Spatial Distribution Characteristics,Source Apportionment,and Risk Assessment of Topsoil PAHs in the Core Area of the Ningdong Energy and Chemical Industry Base[J].Environmental Science,2021,42(5):2490-2501.]
[16] WU W,HU J,WANG J Q,et al.Analysis of Phthalate Esters in Soils near an Electronics Manufacturing Facility and from a Non-Industrialized Area by Gas Purge Microsyringe Extraction and Gas Chromatography[J].Science of the Total Environment,2015,508:445-451.
[17] LIU S S,PENG Y F,LIN Q T,et al.Di-(2-Ethylhexyl) Phthalate as a Chemical Indicator for Phthalic Acid Esters:An Investigation into Phthalic Acid Esters in Cultivated Fields and E-waste Dismantling Sites[J].Environmental Toxicology and Chemistry,2019,38(5):1132-1141.
[18] JIA T Q,GUO W,XING Y,et al.Spatial Distributions and Sources of PAHs in Soil in Chemical Industry Parks in the Yangtze River Delta,China[J].Environmental Pollution,2021,283:117121.
[19] FANG G C,WANG Q L,TIAN L X.Green Development of Yangtze River Delta in China under Population-resources-environment-development-satisfaction Perspective[J].Science of the Total Environment,2020,727:138710.
[20] LI Y,LIU M,LI R K,et al.Polycyclic Aromatic Hydrocarbons in the Soils of the Yangtze River Delta Urban Agglomeration,China:Influence of Land Cover Types and Urbanization[J].Science of the Total Environment,2020,715:137011.
[21] ZHAN Y,SUN J T,LUO Y Z,et al.Estimating Emissions and Environmental Fate of Di-(2-Ethylhexyl) Phthalate in Yangtze River Delta,China:Application of Inverse Modeling[J].Environmental Science & Technology,2016,50(5):2450-2458.
[22] 朱永慧,王倩,黄凌,等.长江三角洲2010-2018年生物质燃烧中等挥发性有机物(IVOCs)排放清单[J].环境科学,2020,41(8):3511-3517.[ZHU Yong-hui,WANG Qian,HUANG Ling,et al.Emission Inventory of Intermediate Volatility Organic Compounds(IVOCs) from Biomass Burning in the Yangtze River Delta during 2010-2018[J].Environmental Science,2020,41(8):3511-3517.]
[23] ZHANG M N,TANG Z W,YIN H M,et al.Concentrations,Distribution and Risk of Polycyclic Aromatic Hydrocarbons in Sediments from Seven Major River Basins in China over the Past 20 Years[J].Journal of Environmental Management,2021,280:111717.
[24] 李静雅,吴迪,许芸松,等.长江三角洲区域表土中多环芳烃的近期分布与来源[J].环境科学,2016,37(1):253-261.[LI Jing-ya,WU Di,XU Yun-song,et al.Recent Distribution and Sources of Polycyclic Aromatic Hydrocarbons in Topsoil of Yangtze River Delta Region[J].Environmental Science,2016,37(1):253-261.]
[25] 葛祥,吴健,高松,等.典型化工集中区环境空气SVOCs污染特征及来源解析[J].环境科学,2021,42(12):5663-5672.[GE Xiang,WU Jian,GAO Song,et al.Pollution Characteristics and Source Analysis of Ambient Air SVOCs in Typical Chemical Concentration Areas[J].Environmental Science,2021,42(12):5663-5672.]
[26] LÜ M Z,GAO W,LI J C,et al.Identification of Zones Contaminated with Phthalates and Polycyclic Aromatic Hydrocarbons by Concentrations in Gridded Soil with 1/6° Latitude by 1/4° Longitude Resolution:A Case Study of Zhejiang,China[J].Journal of Soils and Sediments,2022,22(1):67-78.
[27] 姚林林,张彩香,李佳乐,等.污灌区土壤中多环芳烃的垂直分布及可能来源[J].环境科学,2013,34(4):1553-1560.[YAO Lin-lin,ZHANG Cai-xiang,LI Jia-le,et al.Vertical Distribution and Possible Sources of Polycyclic Aromatic Hydrocarbon in Sewage Area Soil[J].Environmental Science,2013,34(4):1553-1560.]
[28] WANG X T,MIAO Y,ZHANG Y,et al.Polycyclic Aromatic Hydrocarbons (PAHs) in Urban Soils of the Megacity Shanghai:Occurrence,Source Apportionment and Potential Human Health Risk[J].Science of the Total Environment,2013,447:80-89.
[29] 张海光,孙国帅,孙磊,等.典型覆膜作物土壤中邻苯二甲酸酯污染的初步研究[J].中国环境监测,2013,29(4):60-63.[ZHANG Hai-guang,SUN Guo-shuai,SUN Lei,et al.Preliminary Study on Phthalic Acid Esters Pollution of Typical Plastic Mulched Crops Soils[J].Environmental Monitoring in China,2013,29(4):60-63.]
[30] CARTWRIGHT C D,THOMPSON I P,BURNS R G.Degradation andImpact of Phthalate Plasticizers on Soil Microbial Communities[J].Environmental Toxicology and Chemistry,2000,19(5):1253-1261.
[31] MALISZEWSKA-KORDYBACH B.Polycyclic Aromatic Hydrocarbons in Agricultural Soils in Poland:Preliminary Proposals for Criteria to Evaluate the Level of Soil Contamination[J].Applied Geochemistry,1996,11(1/2):121-127.
[32] 冉宗信,陈靖宇,王亚婷,等.典型工业区土壤多环芳烃污染特征及影响因素[J].环境科学,2019,40(10):4594-4603.[RAN Zong-xin,CHEN Jing-yu,WANG Ya-ting,et al.Characteristics and Influencing Factors of Polycyclic Aromatic Hydrocarbons in Surface Soils from Typical Industrial Areas of Chengdu[J].Environmental Science,2019,40(10):4594-4603.]
[33] WEI Y L,BAO L J,WU C C,et al.Association of Soil Polycyclic Aromatic Hydrocarbon Levels and Anthropogenic Impacts in a Rapidly Urbanizing Region:Spatial Distribution,Soil-air Exchange and Ecological Risk[J].Science of the Total Environment,2014,473/474:676-684.
[34] CUI L Z.Residual Analysis and Decomposition of PAES in Soil[J].Environmental Science and Technology,2005,28(4):54-56.
[35] ZHANG Z H,HE G X,PENG X Y,et al.Distribution and Sources of Phthalate Esters in the Topsoils of Beijing,China[J].Environmental Geochemistry and Health,2014,36(3):505-515.
[36] 张慧,郭文建,朱晨,等.不同类型企业周边土壤中多环芳烃来源解析与风险评价[J].环境监测管理与技术,2019,31(4):28-32.[ZHANG Hui,GUO Wen-jian,ZHU Chen,et al.Source Apportionment and Risk Assessment of Polycyclic Aromatic Hydrocarbons in Soils around Different Type of Enterprises[J].The Administration and Technique of Environmental Monitoring,2019,31(4):28-32.]
[37] 邓绍坡,吴运金,龙涛,等.我国表层土壤多环芳烃(PAHs)污染状况及来源浅析[J].生态与农村环境学报,2015,31(6):866-875.[DENG Shao-po,WU Yun-jin,LONG Tao,et al.PAHs Contamination in the Surface Soil of China and Its Sources[J].Journal of Ecology and Rural Environment,2015,31(6):866-875.]
[38] 李春平,陈梦舫,骆永明,等.重点行业的关注污染物与环境危害简析[J].环境监测管理与技术,2011,23(3):7-13.[LI Chun-ping,CHEN Meng-fang,LUO Yong-ming,et al.Contaminants of Concern and Adverse Environmental Impact for Key Industries[J].The Administration and Technique of Environmental Monitoring,2011,23(3):7-13.]
[39] 袁珂月,钱雅慧,许丹丹,等.内蒙古乌达矿区土壤多环芳烃空间分布特征及分析[J]地球与环境,2022,50(5):689-707.[YUAN Ke-yue,QIAN Ya-hui,XU Dan-dan,et al. Distribution Characteristics of Soil PAHs in Wuda Mining Area,Inner Mongolia[J].Earth and Environment,2022,50(5):689-707.]

Pollution Status and Sources of Polycyclic Aromatic Hydrocarbons and Phthalates in Soil of Industrial Parks in Yangtze River Delta

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