新疆油气田开采典型含油废物热解残渣污染特征及来源解析

    Pollution Characteristics and Source Apportionment of Typical Oily Waste Pyrolysis Residue from Oil and Gas Field Exploitation in Xinjiang

    • 摘要: 为探究新疆含油废物热解残渣污染特征、环境风险及污染来源, 共采集研究区域两个油田的含油污泥和含油岩屑的热解残渣(分别为KL-S和KL-D以及TL-S和TL-D)共400份典型样品进行研究, 以期为含油废物热解残渣的环境监管和综合利用污染控制标准制定提供数据支撑。结果表明, 研究区域含油废物热解残渣以Ba、石油溶剂、氟化物和Ni为主要污染物, 其最大值分别为7 270、2 300、970和110 mg·kg-1, Pb、As、Sb、Hg、Se和氰化物等污染物次之, 含量较低。不同油田含油废物热解残渣污染物含量差异较大, 主要受到油气开采过程中化学处理剂及油田开采区域地质背景的影响。同一地质区域的含油废物热解残渣, 可以通过调控热解工艺参数使其不具有危险特性。相关性分析表明, KL-S中Se与Hg(r=-0.70)、Ni与Se(r=0.74)以及KL-D中Se与Ba(r=0.88)均呈现强相关性。除此之外, KL-S、KL-D中多种污染物之间的相关系数r也均超过0.3, 且呈显著水平(P < 0.01), 这表明克拉玛依油田含油废物热解残渣污染物可能具有相同来源。主成分分析结果表明, KL-S、KL-D可以分别筛选出3个主成分, 其主成分累积贡献率分别为71.46%和63.39%。主成分中重金属载荷较高, 主要来源于油气开采过程的化学处理剂和开采区域的自然地质背景。

       

      Abstract: To investigate the pollution characteristics, environmental risks, and contamination sources of pyrolysis residues from oily waste in Xinjiang, a total of 400 typical samples were collected from two oilfields in the study area. The sample matrix encompassed pyrolysis residues of oily sludge and oil-based drill cuttings (denoted as KL-S and KL-D, TL-S and TL-D). It is expected that this study will provide data support for the environmental regulation and comprehensive utilization of pollution control standards for the pyrolysis residue of oily waste. The results show that Ba, petroleum solvent, fluoride, and Ni were the main pollutants in the pyrolysis residue of oily waste in the study area, with maximum values of 7 270, 2 300, 970, and 110 mg·kg-1, respectively. Other pollutants, such as Pb, As, Sb, Hg, Se, cyanide, exhibited relatively lower concentrations. There are significant differences in the pollutant content of pyrolysis residues from oily waste in different oil fields, mainly influenced by chemical treatment agents during oil and gas extraction and the geological background of the oil field extraction area. By adjusting the pyrolysis process parameters, the pyrolysis residues in the same geological area could be rendered non-hazardous. Correlation analysis show that there was a strong correlation between Se and Hg (r=-0.70), Ni and Se (r=0.74) in KL-S, and Se and Ba (r=0.88) in KL-D. In addition, the correlation coefficients of various pollutants in KL-S and KL-D were all higher than 0.3, and the level was significant (P < 0.01), indicating that the pollutants in the pyrolysis residue of oily waste in Karamay Oilfield had the possibility of the same source. The results of principal component analysis indicate that KL-S and KL-D could respectively screen out three principal components, with cumulative contribution rates of 71.46% and 63.39%, respectively. The heavy metal load in the principal components was relatively high, mainly derived from chemical treatment agents used in oil and gas extraction processes and the natural geological background of the extraction area.

       

    /

    返回文章
    返回