猪和奶牛粪污厌氧发酵中固相磷形态变化分析

    Variation in Forms of Solid Phase Phosphorus in Pig and Dairy Cow Manures Under Anaerobic Digestion

    • 摘要: 采用H2O、NaHCO3、NaOH和HCl连续抽提法分析了猪和奶牛粪污厌氧发酵前后固相磷的形态和含量。结果表明,猪粪厌氧发酵后的出料(沼液)固相中HCl-P所占比例为85.50%,较进料显著提高(P<0.05);NaHCO3提取态磷(NaHCO3-P)、残留磷、H2O-P和NaOH溶性磷(NaOH-P)所占比例分别为5.83%、4.71%、2.15%和1.81%,均较进料有不同程度降低。牛粪厌氧发酵后排放的沼液固相中HCl-P、NaHCO3-P、H2O-P、残留磷和NaOH-P所占比例分别为53.73%、19.62%、12.66 %、8.60%和5.39%,均较进料无显著变化。沼液固相中各形态无机磷占总磷的比例为60.98%~100.00%。厌氧发酵运行结束后,猪粪沼渣固相中各形态磷含量由高到低依次为HCl-P、NaHCO3-P、残留磷、H2O-P和NaOH-P,分别占沼渣固相总磷的87.43%、5.17%、4.33%、1.79%和1.28%;牛粪沼渣固相中各形态磷含量由高到低依次为HCl-P、NaHCO3-P、H2O-P、残留磷和NaOH-P,分别占沼渣固相总磷的69.74%、9.91%、8.75%、8.30%和3.30%。猪粪经厌氧发酵后,磷由液相向固相转移,而固相中水溶态磷向难溶态磷转化;牛粪沼渣中的磷较猪粪沼渣中的磷更难被作物吸收利用。

       

      Abstract: Forms and contents of solid-phase phosphorus in pig and dairy cow manures before and after subjection to anaerobic digestion were analyzed, using the sequential extraction method with H2O, NaHCO3, NaOH and HCl. Results show that in the effluent slurry from pig dung digesters, HCl-P accounted for 85.50% of the total solid-phased phosphorus (TSP), significantly higher than that in the influent material (P<0.05);.whereas NaHCO3-P, residual P, H2O-P and NaOH-P did for 5.83%, 4.71%, 2.15% and 1.81%, respectively, all lower than their corresponding one in the influence to a varying extent; and in the effluent slurry from dairy cow manure digesters,. HCl-P, NaHCO3-P, H2O-P, residual P and NaOH-P accounted for 53.73%, 19.62%, 12.66 %, 8.60% and 5.39%, respectively, which did not differed much from that in the influent manure. The inorganic phosphorus in the slurry accounted for 60.98% - 100.00% of TSP. After anaerobic digestion, solid-phased phosphorus of various forms in the digestion sludge from the pig dung digesters displayed an order of HCl-P > NaHCO3-P > residual P > H2O-P > NaOH-P in content, each accounting for 87.43%, 5.17%, 4.33%, 1.79% and 1.28%, respectively, in percentage of TSP, respectively; while a different order was found in the digestion sludge from the dairy cow manure digesters, that is, HCl-P > NaHCO3-P > H2O-P > residual P > NaOH-P, each accounting for 69.74%, 9.91%, 8.75%, 8.30% and 3.30%, respectively. After anaerobic digestion of pig dung, liquid-phased phosphorus was transformed into solid-phased one and water-soluble P in the latter turned into insoluble P. However, phosphorus in digested dairy cow slurry was less available to plants than that in digested dairy cowpig dung slurry.

       

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