恶唑酰草胺在稻田中的残留及消解动态

    Residue and Degradation of Metamifop in Paddy Field

    • 摘要: 借助加速溶剂提取、凝胶渗透色谱净化和液相色谱测定方法,研究了南京和南昌两地稻田施用w为10%的恶唑酰草胺乳油后,其有效成分恶唑酰草胺在稻田中的残留及消解动态。结果表明,恶唑酰草胺在水稻植株、稻田土壤及稻田水中的消解较快,在南京和南昌两地水稻植株中的消解半衰期分别为3.5和2.2 d,在稻田土壤中的消解半衰期分别为11.7和20.2 d,在稻田水中的消解半衰期分别为1.3和2.3 d。在稻田中按照最高推荐剂量和最高推荐剂量的2倍施用恶唑酰草胺乳油,施药1次,在收货的稻秆、稻壳、糙米及稻田土壤中均未检出恶唑酰草胺。这说明恶唑酰草胺为低残留、易降解农药。

       

      Abstract: Field experiments were conducted in Jiangxi and Jiangsu Provinces,separately,of spraying metamifop(10% emulsifiable solution)in paddy fields to explore dynamics of metamifop residus in the paddy fields with the accelerated solvent extraction(ASE),gel permeation chromatography(GPC) and high performance liquid chromatography(HPLC)methods.Results show that metamifop degraded quickly in the plant and water,but not so in the soil.The half-life of metamifop in plant,water and soil was approximately 3.5 and 2.2 days,1.3 and 2.3 days,11.7 and 20.2 days at Nanjing and Nanchang,respectively.When a paddy field was sprayed once with 10% metamifop emulsifiable solution at the highest recommended dose and even 2 times of that value,no residue of the substance was detected in rice straw,rice hull,brown rice and paddy soil at the harvest,which suggests that metamifop is a kind of pesticide low in residue and easy to degrade.

       

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