人居生活废弃物生物黑炭对水溶液中Cd2+的吸附研究

Adsorption of Cadmium in Solution by Biochar From Household Biowaste

  • 摘要: 以人居生活废弃物生物黑炭为材料,探讨生物黑炭对Cd2+的吸附动力学及热力学特性,通过平衡吸附法研究吸附时间、Cd2+初始质量浓度、吸附剂投加量、溶液pH值以及黑炭粒径对Cd2+吸附率的影响。结果表明,吸附时间为2h时基本达到吸附平衡,准二级动力学方程能很好地描述生物黑炭对Cd2+的吸附过程。Langmuir模型能较好地描述生物黑炭对Cd2+的等温吸附过程,根据该模型模拟得到25℃条件下Cd2+最大吸附量为6.22 mg·g-1。Cd2+去除率随生物黑炭投放量的增加而增大;生物黑炭对Cd2+吸附量随其粒径减小而增大;溶液初始pH值为4.0~7.5时,pH值变化对Cd2+吸附量的影响不显著。采用人居生活废弃物生物黑炭去除水溶液中Cd2+时,控制溶液Cd2+初始质量浓度30mg·g-1,粒径小于0.25mm,投加水平8g·L-1,反应温度25℃,反应时间1~2h,Cd2+去除率可达80%。人居生活废弃物生物黑炭可以作为去除污染水体中Cd2+的吸附剂。

     

    Abstract: Biochar produced via pyrolysis of housedhold biowaste was used as an adsorbent in an experiment to study kinetics and thermodynamics of its adsorption of Cd2+ in solution and to explore effects of incubation time,initial Cd2+ cocentration,adsorbent dosage,solution pH as well as particle size of biochar on its Cd2+ adsorption rate with the equilibrium adsorption method.Results show that the adsorption basically reached equilibrium after 2 h and the process could be well described with the pseudo second order dynamic equation.The adsorption curves followed an isothermic adsorption model,which could be weel described with the Langmuir model.The Cd2+ adsorption peaked at 25℃,reaching 6.22 mg·g-1 as simulated with the Langmuir model.Cd2+ removal rate increased with increasing dosage of biochar and decreasing particle size of bilchar.The effect of pH on Cd2+ adsorption capacity was not obvious when initial pH of the solution was 4.0-7.5.When biochar is used to remove Cd2+ from wastewater,it is advisable to control the initial Cd2+ concentration at 30mg·g-1,particle size of the biochar at <0.25mm,dosage of the biochar at 8g·L-1,reaction temperature at 25℃,and duration of the reaction at 1-2 h.In this case,the Cd2+ removal rate can be as high as 80%.This indicates that biochar made from household biowaste can be as adsorbent to remove Cd2+ in polluted water.

     

/

返回文章
返回