Abstract:
Heavy metal ions Cd
2+ were adsorbed by potassium-permanganate-modified wheat straw. The modified wheat straw was characterized by scanning electron microscopy, zeta potential, and Fourier transform infrared spectroscopy. The effects of pH, adsorption time, solid-liquid ratio, and temperature of the solution and desorption on Cd
2+ adsorption were also studied. Four different concentrations of potassium-permanganate-modified wheat straw were observed. Results show that, compared with the surfaces of other concentrations, the surface of 0.05 mol·L
-1 potassium-permanganate-modified wheat straw appeared smoother and had more negative charges. These outcomes were beneficial to improving the adsorption performance of Cd
2+. Moreover, the adsorption reached equilibrium at 300 min and fitted the pseudo two-order kinetic equation. The best adsorption effect was obtained when the pH of the modified wheat straw was 6, and the solid-liquid ratio was 1:300. According to the Langmuir isothermal adsorption equation, the adsorbents prepared using the modified adsorbents of 0.05 mol·L
-1 had the largest adsorption capacity for Cd
2+ (30.21 mg·g
-1) far larger than the optimum adsorption capacity of the unmodified wheat straw (5.7 mg·g
-1). The adsorbent has been found to have good stability for Cd
2+ adsorption.