南京市城郊蔬菜生产基地有机氯农药残留特征

Characteristics of Organochlorine Pesticide Residue in Soils in Baguazhou Non-Polluted Food Base in Nanjing

  • 摘要: 以网格法在南京市无公害蔬菜生产基地八卦洲采集70个土壤样品,用加速溶剂萃取、固相萃取柱净化后GC-μECD测定土壤中有机氯农药(α-HCH,β-HCH,γ-HCH和δ-HCH以及o,p′-DDT,p,p′-DDT,o,p′-DDE,p,p′-DDE和p,p′-DDD)残留量。结果表明,土壤中有机氯农药残留总量在6.18~84.72μg.kg-1之间,平均18.63μg.kg-1。DDT残留量高于HCH,为3.36~74.19μg.kg-1,平均12.61μg.kg-1。土壤中HCH残留量为2.48~17.80μg.kg-1,平均6.02μg.kg-1。DDT同系物中以p,p′-DDE和p,p′-DDT为主,而HCH中δ-HCH含量较低,其他3种异构体含量水平相当。所有土样中DDT和HCH残留量均远远低于GB/T18407无公害蔬菜产地土壤标准限定值500μg.kg-1,但大多数土样中DDT和HCH残留量远远高于荷兰无污染土壤标准。

     

    Abstract: In order to investigate the soil quality in non-polluted food bases in Nanjing,a total of 70 soil samples were collected from the surface soil layer in Baguazhou,Nanjing for analysis of residues of organochlorine pesticides(OCPs)(α-,β-,γ-,and δ-HCH,o,p′-DDT,p,p′-DDT,o,p′-DDE,p,p′-DDE,and p,p′-DDD) and their characteristics.OCPs were extracted by ASE(accelerated solvent extractor) with acetone/petroleum ether(1/4,V/V),cleaned up with silica gel column and quantified by capillary gas chromatography with a 63Ni electron capture detector(GC-μECD).Results show that total OCPs residues in the soils ranged between 6.18 and 84.72 μg·kg-1,averaging 18.63 μg·kg-1.The concentration of DDT was much higher than that of HCH in soils.DDT residues ranged from 3.36 to 74.19 μg·kg-1 with an average being 12.61 μg·kg-1,while HCH residue did from 2.48 to 17.80 μg·kg-1 with an average being 6.02 μg·kg-1.Both DDT and HCH in all the soil samples were far below the threshold value of 500 μg·kg-1 in the Chinese "Non-Polluted Food Base Soil Quality Standards".However,most of them were much higher than the criteria for non-polluted soils in the "Guideline for Soil Protection of the Netherlands".

     

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