AI驱动生活垃圾填埋场邻苯二甲酸(2-乙基己基)酯(DEHP)迁移的因果识别研究

AI-Driven Causal Identification of Di(2-ethylhexyl) Phthalate (DEHP) Migration in Municipal Solid Waste Landfills

  • 摘要: 随着我国生活垃圾填埋量的持续增长以及塑料制品广泛使用, 增塑剂邻苯二甲酸(2-乙基己基)酯〔di-(2-ethylhexyl)phthalate, DEHP〕等新型污染物在填埋环境中赋存与迁移问题日益严重, 尤其是在缺乏防渗等工程措施的非正规生活垃圾填埋场中污染风险更加隐蔽与复杂。针对传统分析方法难以揭示污染驱动机制的问题, 该研究引入因果森林(causal forest)模型, 构建因果推理框架, 系统评估了填埋场基础属性、土壤理化性质、重金属污染背景及填埋体物理组分等多类环境因子对DEHP迁移行为的因果效应及层级异质性。结果表明, DEHP迁移过程具有显著的非线性响应特征和分层敏感性, 填埋龄在低龄组强烈促进迁移(平均处理效应ATE=4.32), 在高龄组效应转为负值(ATE=-0.16);pH在高值范围时抑制效应最强(ATE=-5.66);重金属Cd与Hg在底层土壤中表现为显著协同迁移潜势(ATE分别达49.49与54.80);填埋深度、有机质等因子效应较弱或存在阈值变化; 橡塑类组分在中等占比时微弱促进迁移(ATE=0.15), 灰土类组分则持续抑制迁移(ATE=-1.61~-0.41)。研究结果验证了因果机器学习在复杂污染系统中的识别能力, 并为非正规填埋场污染控制、风险分区和源头干预提供了新型工具支持, 推动填埋场污染控制由"相关归因"向"因果调控"转变, 可为实现精准、机制导向的固废污染治理提供理论与方法支撑。

     

    Abstract: With the continued expansion of domestic waste landfilling and the pervasive use of plastic products in China, the occurrence and migration of emerging pollutants such as di(2-ethylhexyl) phthalate (DEHP) in landfill environments have become increasingly severe, particularly at informal landfills, where the absence of engineered measures (e.g., anti-seepage systems) leads to more concealed and complex pollution risks. To address the limitations of traditional correlation-based methods in uncovering pollution-driving mechanisms, this study introduces a causal forest model to establish a causal inference framework. The model is used to systematically evaluate the causal effects and stratified heterogeneity of multiple environmental factors, including landfill characteristics, soil physicochemical properties, heavy metal contamination, and waste composition on DEHP migration. The results show that the migration process of DEHP exhibited significant nonlinear response characteristics and stratification sensitivity. The landfill age strongly promoted migration in the younger group (average treatment effect ATE=4.32), while the effect turned negative in the older group (ATE=-0.16). The inhibitory effect is strongest when the pH is in a high range (ATE=-5.66). The heavy metals Cd and Hg exhibited significant synergistic migration potential in the bottom soil layers, with ATE values as high as 49.49 and 54.80, respectively. In contrast, factors such as landfill depth and organic matter have weaker effects or threshold changes; Rubber and plastic components weakly promote migration at a moderate proportion (ATE=0.15), while ash and soil components continuously inhibit migration (ATE=-1.61--0.41). This study demonstrates the capacity of causal machine learning to identify pollution drivers in complex systems, offering a novel analytical tool for pollution control, risk zoning, and source intervention in informal landfills. It supports a paradigm shift from correlation-based attribution to mechanism-driven causal regulation, providing theoretical and methodological guidance for achieving precise and targeted solid waste pollution management.

     

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