中国南方城市湖泊水化学特征及影响因素

Hydrochemical Characteristics and Influencing Factors of Urban Lakes in Southern China

  • 摘要: 南昌市是我国南方典型的滨水城市,其城市湖泊水化学组成受人为活动严重影响。当前,对南昌城市湖泊的水化学特征及其影响因素的研究较空缺。本研究以南昌典型城市湖泊(瑶湖、艾溪湖、青山湖、象湖)及河流(赣江、抚河)为研究对象,分析了其2020年11月—2021年10月水体pH值、电导率(EC)、总溶解固体(TDS)及阴、阳离子浓度,结合相关性分析、主成分分析、Gibbs图及离子比值法,揭示了城市湖泊水化学特征及其影响因素。结果表明,南昌城市湖泊pH值为7.81~8.05,TDS为110~364 mg·L-1,艾溪湖水化学特征因工业污染呈现独特的SO42--HCO3--Mg2+-Ca2+-Na+型,其他湖泊水体以HCO3--SO42--Ca2+-Na+型为主。与河流水化学特征不同,湖泊水化学离子浓度呈雨季下降的特征,8月达最低,表明雨季冲刷减少了人为污染物输入。多元统计分析显示,外围湖泊(瑶湖、象湖)受硅酸盐风化影响显著,而城市中心湖泊(艾溪湖、青山湖)主要受工业污染、市政污水及农业化肥施用等人为活动影响。研究揭示了我国南方城市湖泊水化学特征的复杂性,强调了人为活动对城市湖泊水质的显著影响,为城市水环境管理提供了科学依据。

     

    Abstract: Nanchang, a typical waterfront city in Southern China, experiences substantial anthropogenic influences on the hydrochemistry of its urban lakes. However, there is a lack of research on the impacts and underlying controls. In this study, the Nanchang urban lakes (Yaohu Lake, Aixihu Lake, Qingshanhu Lake and Xianghu Lake) and rivers (Ganjiang River and Fuhe River) were taken as the objects. Combined with correlation analysis, principal component analysis (PCA), Gibbs diagrams, and ion ratios, the pH, electrical conductivity (EC), total dissolved solids (TDS), and anion/cation concentrations of water samples collected from November 2020 to October 2021 were studied to reveal the hydrochemical characteristics and their influencing factors. Results show that the Nanchang urban lakes had a slightly alkaline pH range (7.81-8.05) and TDS values were 110-364 mg·L-1. Aixihu Lake exhibited a unique hydrochemical type of SO42--HCO3--Mg2+-Ca2+-Na+ due to industrial pollution, while other lakes were predominantly of the HCO3--SO42--Ca2+-Na+ type. Unlike the rivers, the ionic concentrations of lakes showed decreasing trends during the rainy season with the lowest levels in August, indicating reduced anthropogenic pollutant inputs from rainy season flushing. Multivariate analysis reveals that peripheral lakes (Yaohu, Xianghu) were significantly influenced by silicate weathering, whereas central urban lakes (Aixihu, Qingshanhu) were predominantly affected by anthropogenic activities like industrial pollution, municipal sewage, and agricultural fertilizer. This study highlights the complexity of hydrochemical characteristics in Southern China′s urban lakes, underscores the substantial impact of human activities on water quality, and provides a scientific basis for urban water environment management.

     

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