硫铁矿渣路基应用的风险评估与管控

Risk Assessment and Management of Pyrite Cinder in Roadbed Applications

  • 摘要: 固体废物资源化利用的环境风险评估普遍依赖于过度简化的模型框架, 往往忽略了污染物释放机制的复杂性和地域环境的多样性, 因而难以精准刻画各类气候区(干旱、半干旱、半湿润、湿润)中固体废物资源化利用的环境风险。本研究融合源强指数衰减与污染物瞬时迁移模型, 并引入蒙特卡罗模拟技术, 旨在探讨硫铁矿渣在道路建设中的资源化利用途径及其在各类气候区的潜在环境风险。研究结果表明, 硫铁矿渣中砷、锰、镍和镉4种重金属污染物的潜在危害指数(PHI)值为3.3~14.2, 潜在危害显著。重金属砷在地下水中迁移转化后, 其浓度存在超标风险(超标概率为27%), 暴露浓度(95%置信水平浓度值, 0.034 mg·L-1)超出GB/T 14848-2017《地下水质量标准》中对应Ⅲ类限值的3.4倍。研究发现降雨量增加会加剧重金属浸出风险, 通过调整硫铁矿渣在路基垫层中的掺配比例可有效管理风险, 湿润气候区硫铁矿渣掺配比例应控制在30%以下, 半湿润气候区硫铁矿渣掺配比例不应超过40%。本研究指出传统评估方法在污染物释放潜力及峰值风险评估方面存在不足, 亟须加快构建完善的固废资源化风险评估与管控标准体系, 并针对不同区域实施差异化的管理策略。

     

    Abstract: Environmental risk assessments for the resource products of solid waste generally rely on oversimplified model frameworks. These frameworks often overlook the complexity of pollutant release mechanisms and the diversity of regional environments, making it difficult to accurately characterize the environmental risks of solid waste resource utilization across various climatic zones (arid, semi-arid, semi-humid, humid). Integrating the source strength index decay model with the pollutant instantaneous migration model, and introducing Monte Carlo simulation techniques, this study aims to explore the resource utilization pathway of pyrite cinder in road construction and its potential environmental risks in different climatic zones. Results show that the potential hazard index (PHI) of four heavy metal pollutants (arsenic, manganese, nickel, and cadmium) in pyrite cinder ranges from 3.3 to 14.2, indicating significant potential hazards. After migration and transformation in groundwater, arsenic has an exceedance risk (exceedance probability of 27%), with the exposure concentrations (0.034 mg·L-1) 3.4 times higher than the Class Ⅲ limit specified in Groundwater Quality Standard (GB/T 14848-2017). The study finds that increased rainfall intensifies the leaching risk of heavy metals, which can be effectively managed by adjusting the mixing ratio of pyrite cinder in roadbed subbase layers. The mixing ratio should be controlled below 30% in humid climatic zones and no more than 40% in semi-humid climatic zones. Traditional assessment methods are insufficient in evaluating pollutant release potential and peak risks. It is urgent to accelerate the establishment of a comprehensive risk assessment and control standard system for solid waste resource utilization, and implement differentiated management strategies for different regions.

     

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