鄂东南富水水库沉积柱中多环芳烃(PAHs)的垂直分布、来源及生态风险评价

Vertical Distribution, Sources and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in Sediment Cores from the Fushui Reservoir in Southeastern Hubei, China

  • 摘要: 沉积柱中的多环芳烃(PAHs)因具有难降解性和鲜明的来源特征, 可有效记录历史污染过程。本研究以鄂东南第一大水库--富水水库为研究区域, 采集了4根沉积柱样品, 使用气相色谱-质谱联用仪(GC-MS)对16种优控PAHs进行了检测, 分析了其垂直浓度分布、来源及风险。结果表明, 沉积柱中16种PAHs(Σ16PAHs)浓度范围为69.4~457 ng·g-1, 且以中高环PAHs组分为主。在空间上, 位于河流入库口处的沉积柱中Σ16PAHs浓度较高, 这可能主要是由于该区域人类活动较多。从历史时间上看, Σ16PAHs浓度整体上呈早期上升而后期下降的趋势, 这与区域社会经济发展历程及随后加强的环境治理措施相吻合。源解析结果表明, 富水水库中PAHs主要来源为石油及其燃烧、煤炭/生物质燃烧和交通排放。生态风险评价结果显示, 富水水库沉积柱中PAHs整体为低至中毒性风险, 且近年来风险呈下降趋势。本研究结果可为富水水库及周边水环境的污染防控和综合治理提供科学依据和理论指导。

     

    Abstract: Undisturbed sediment cores can provide a record of changing environmental conditions and pollution levels. Polycyclic aromatic hydrocarbons (PAHs) in sediment cores can serve as indicators of the historical pollution processes due to their persistence and distinct source characteristics. In this study, changes in polycyclic aromatic hydrocarbons (PAHs) were studied in four sediment cores from the Fushui Reservoir, the largest reservoir in southeastern Hubei Province, and changes with depth interpreted with respect to their changing sources and environmental processing. The results showed that the total concentrations of 16 PAHs (Σ16PAHs) ranged from 69.4 to 457 ng·g-1, with medium- and high-molecular-weight PAHs being dominant. The highest concentrations of Σ16PAHs in the sediment core were observed at the river inlet to the reservoir, which may be caused by the intensive anthropogenic activities in this area. Temporally, the concentrations of Σ16PAHs continuously increased since the 1950s, peaked after the 1980s, and declined after 2010, which corresponded to the progress of socioeconomic development and the implementation of environmental governance measures. Source analysis revealed that PAHs in the Fushui Reservoir primarily originated from petroleum sources, petroleum combustion, coal/biomass combustion, and traffic emissions, which may be transported into the reservoir via catchment surface runoff and atmospheric deposition. Ecological risk assessment indicated that the PAHs in the sediment cores from the Fushui Reservoir posed low to moderate risks, with a declining trend in recent years. The findings of this study can provide a scientific basis and theoretical support for pollution prevention and integrated management of the Fushui Reservoir and its surrounding water environment.

     

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