天津地区环境持久性药物污染物残留水平调查

doi:10.19741/j.issn.1673-4831.2019.0053

生态与农村环境学报 ›› 2019, Vol. 35 ›› Issue (10): 1274-1281.doi: 10.19741/j.issn.1673-4831.2019.0053

天津地区环境持久性药物污染物残留水平调查

孟迪^1,2, 汪贞¹, 古文¹, 周林军¹, 范德玲¹, 王冬梅³, 刘济宁¹, 石利利¹

1. 生态环境部南京环境科学研究所, 江苏南京 210042;
2. 南京工业大学化学与分子工程学院, 江苏南京 210009;
3. 天津市固体废物及有毒化学品管理中心, 天津 300191

收稿日期:2019-01-26 出版日期:2019-10-25 发布日期:2019-10-23
通讯作者: 范德玲, 王冬梅 E-mail:fdl@nies.org;tjwangdongmei@126.com
作者简介:孟迪(1994-),女,安徽阜阳人,硕士生,主要从事环境分析。E-mail:1099644094@qq.com
基金资助:
国家重点研发计划（2018YFC1801601）

Investigation on the Residual Level of Environmentally Persistent Pharmaceutical Pollutants in Tianjin City

MENG Di^1,2, WANG Zhen¹, GU Wen¹, ZHOU Lin-jun¹, FAN De-ling¹, WANG Dong-mei³, LIU Ji-ning¹, SHI Li-li¹

1. Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China;
2. Collage of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 210009, China;
3. Tianjin Solid Waste and Toxic Chemicals Management Center, Tianjin 300191, China

Received:2019-01-26 Online:2019-10-25 Published:2019-10-23

摘要/Abstract

摘要： 针对环境持久性药物污染物（EPPPs）的污染问题，采用固相萃取-高效液相色谱/串联质谱法，调查分析了22种环境持久性药物污染物在天津地区水体和沉积物中的残留水平和分布特征。结果显示，水源地水样中有19种EPPPs的检出率为100%，质量浓度范围为0.21~0.69 μg·L^-1，平均值为0.43 μg·L^-1。地表水样中，除吉他霉素检出率为80%外，其余21种EPPPs的检出率均为100%，质量浓度范围为0.52~3.88 μg·L^-1，平均值为1.60 μg·L^-1。沉积物样中共检出11种EPPPs，检出率为100%，含量范围为0.04~1.10 μg·kg^-1，平均值为0.52 μg·kg^-1。其中蓟县于桥水库、蓟运河滨海新区段水样和独流减河滨海新区段沉积物样中检出的EPPPs残留水平较高，水体中环丙沙星、诺氟沙星与菲诺洛芬检出浓度较高，沉积物中则为吲哚美辛、水杨酸及氟苯尼考。对比国内外其他地区，天津地区水环境中EPPPs残留处于较高水平。

关键词: 固相萃取, 高效液相色谱-串联质谱, 环境水体与沉积物, 环境持久性药物污染物(EPPPs)

Abstract: Accroding to the pollution problem of environmental persistent pharmaceutical pollutants (EPPPs), the residual levels and distribution characteristics of 22 kinds of environmental persistent pharmaceutical drug contaminants in water and sediments in Tianjin were investigated by solid phase extraction-high-performance liquid chromatography/tandem mass spectrometry. The results display that the detection rate of 19 kinds of EPPPs was 100% in the water samples from sources, and the concentration range and average concentration were 0.21-0.69 and 0.43 μg·L^-1, respectively. As shown in the surface water samples except for kitasamycin (80%), the detection rate for other 21 kinds of EPPPs was all 100%. Moreover, the concentration range of these EPPPs was from 0.52 to 3.88 μg·L^-1 and the average concentration was 1.60 μg·L^-1. Furthermore, 11 kinds of EPPPs were detected completely (100%) in the sediments and the concentration range and average concentration were 0.04-1.10 and 0.52 μg·kg^-1. Among the above results, the EPPPs residue levels of water samples in the Yuqiao reservoir of Jixian county, Jiyunhe of New Binhai section and sediments in the Duliujian river basin of New Binhai section were the highest. Compared with other EPPPs, the concentrations of ciprofloxacin, norfloxacin, fenoprofen in the water and indomethacin, salicylic acid, florfenicol in sediments were high. In summary, EPPPs residues level of water in Tianjin was higher than other regions in China and other countries.

Key words: solid phase extraction, high performance liquid chromatography-tandem mass spectrometry, environmental water and sediment, environmental persistent pharmaceutical pollutants(EPPPs)

中图分类号:

X824

孟迪, 汪贞, 古文, 周林军, 范德玲, 王冬梅, 刘济宁, 石利利. 天津地区环境持久性药物污染物残留水平调查[J]. 生态与农村环境学报, 2019, 35(10): 1274-1281.

MENG Di, WANG Zhen, GU Wen, ZHOU Lin-jun, FAN De-ling, WANG Dong-mei, LIU Ji-ning, SHI Li-li. Investigation on the Residual Level of Environmentally Persistent Pharmaceutical Pollutants in Tianjin City[J]. Journal of Ecology and Rural Environment, 2019, 35(10): 1274-1281.

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天津地区环境持久性药物污染物残留水平调查

Investigation on the Residual Level of Environmentally Persistent Pharmaceutical Pollutants in Tianjin City

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