生态与农村环境学报 ›› 2010, Vol. 26 ›› Issue (3): 251-256.doi: CNKI:SUN:NCST.0.2010-03-015

• 污染控制与修复 • 上一篇    下一篇

外源重金属在珠江河口湿地土壤中的形态转化

陈小娇, 李取生, 杜烨锋, 杨芳兵   

  1. 暨南大学环境工程系
  • 收稿日期:2009-09-20 出版日期:2010-05-25 发布日期:2011-04-01
  • 通讯作者: 李取生 暨南大学环境工程系 E-mail:liqusheng@21cn.com
  • 作者简介:陈小娇(1983-),女,安徽安庆人,硕士生,主要从事环境生态与土壤环境方面的研究。E-mail: xiaojiaochen07@126.com
  • 基金资助:

    国家自然科学基金(U0833002,40871154);广东省自然科学基金(07005931)

Transformation of Forms of Extrogenous Heavy Metals in Wetland Soil at the Pearl River Estuary

CHEN  Xiao-Jiao, LI  Qu-Sheng, DU  Ye-Feng, YANG  Fang-Bing   

  1. Department of Environmental Engineering, Jinan University
  • Received:2009-09-20 Online:2010-05-25 Published:2011-04-01
  • Contact: LI Qu-Sheng Department of Environmental Engineering,Jinan University E-mail:liqusheng@21cn.com

摘要: 采集珠江口湿地土壤,采用室内培养和Tessier化学逐级连续浸提方法研究了外源重金属在珠江河口湿地土壤中的化学形态转化,探讨了盐分变化对重金属形态转化的影响。试验结果表明,外源重金属进入珠江河口湿地土壤后主要以可利用态和潜在可利用态存在,Ni、Zn、Cu、Cr和Pb主要向铁锰氧化物结合态转化,而Cd主要向可交换态和碳酸盐结合态转化。土壤盐分含量递增对重金属Cu、Zn、Ni和Cr的形态分布无显著影响,对重金属Pb和Cd的影响主要体现在可交换态。在土壤盐分添加量不超过80 g.kg-1时,随着土壤含盐量的上升,土壤Cd和Pb的可交换态比例逐步增大。

关键词: 外源重金属, 形态转化, 盐分, 土壤, 湿地

Abstract: Transformation of chemical forms of extrogenous heavy metals in the wetland soil collected from the Pearl River Estuary were studied using laboratory incubation and the Tessier chemical fractionation method to explore effects of salinity on their chemical forms in the soil.Results show that extrogenous heavy metals existed in the wetland soil mainly in available or potentially available form,but after eight months of incubation,very little remained to be in residual form.With increasing loads of heavy metals in the soil,the percentage of residual form decreased,while the percentages of the other four fractions increased.Ni,Zn,Cu,Cr and Pb tended to be bound with Fe-Mn oxides,while Cd to be transformed into exchangeable form or bound into carbonate.Soil salinity did not have much impact on Cu,Zn,Ni and Cr in fractionation,but did on Pb and Cd,particularly their exchangeable forms.Exchangeable forms of Cd and Pb in the soil increased with increasing soil salinity until soil salt reached 80 g·kg-1.

Key words: extrogenous heavy metal, fraction transformation, salinity, soil, wetland

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