壳聚糖活性污泥复合吸附剂处理铅、镉废水研究

doi:10.11934/j.issn.1673-4831.2017.08.008

生态与农村环境学报 ›› 2017, Vol. 33 ›› Issue (8): 730-736.doi: 10.11934/j.issn.1673-4831.2017.08.008

壳聚糖活性污泥复合吸附剂处理铅、镉废水研究

赵佐平^1,2, 段敏^1,2, 刘智峰^1,2, 汤波^1,2, 同延安³

1. 陕西理工大学化学与环境科学学院, 陕西汉中 723001;
2. 陕南秦巴山区生物资源综合开发协同创新中心, 陕西汉中 723001;
3. 西北农林科技大学资源环境学院, 陕西杨凌 712100

收稿日期:2016-08-19 出版日期:2017-08-25 发布日期:2017-09-25
通讯作者: 同延安,E-mail:tongyanan@nwsuaf.edu.cn E-mail:tongyanan@nwsuaf.edu.cn
作者简介:赵佐平(1982-),男,陕西旬阳人,博士,主要从事环境监测等方面的研究。E-mail:zhaozuoping@126.com
基金资助:
国家公益性行业科研专项（201203045）；陕西省2011协同创新中心项目〔QBXT-Z（P）-15-5〕；2016年国家级大学生创新创业训练计划（201610720009）

Research on Adsorption Performance of Chitosan-Activated Sludge Composite Adsorbent to Cadmium and Lead in Wastewater

ZHAO Zuo-ping^1,2, DUAN Min^1,2, LIU Zhi-feng^1,2, TANG Bo^1,2, TONG Yan-an³

1. College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China;
2. Qinba Mountains Bio-Resource Collaborative Innovation Center of Southern Shaanxi Province, Hanzhong 723001, China;
3. College of Natural Resources and Environment, Northwest A & F University, Yangling 712100, China

Received:2016-08-19 Online:2017-08-25 Published:2017-09-25

摘要/Abstract

摘要：

研究了壳聚糖活性污泥复合吸附剂（SCTS）对废水中Pb²⁺和Cd²⁺的吸附性能，通过单因素试验分析了温度、SCTS投加量、pH值、搅拌转速和重金属离子浓度对SCTS吸附性能的影响，正交试验确定了影响因素的主次顺序及最优组合水平。结果表明：影响SCTS吸附废水中Pb²⁺的因素从大到小依次为pH值、SCTS投加量、Pb²⁺初始浓度和搅拌转速，吸附Pb²⁺的最优组合为pH值=2、SCTS投加量为10 g·L^-1、ρ（Pb²⁺）初始值为50 mg·L^-1、搅拌转速130 r·min^-1，Pb²⁺去除率达95.76%。影响SCTS吸附废水中Cd²⁺的因素作用力大小依次为pH值、Cd²⁺初始浓度、转速和SCTS投加量，吸附Cd²⁺的最优组合为pH值2、SCTS投加量2.5 g·L^-1、ρ（Cd²⁺）初始值60 mg·L^-1、转速130 r·min^-1，此时Cd²⁺的去除率为96.08%。

关键词: 壳聚糖, 复合吸附剂, 镉, 铅, 废水, 吸附

Abstract:

The adsorption performance of the chitosan-activated sludge composite adsorbent on cadmium and lead in wastewater was examined, and the influencing factors, such as temperature, SCTS addition, pH, rotate speed and the concentration of heavy metals were investigated in a single factor experiment, thus the order of influencing factors and the optimal combination were determined in an orthogonal experiment. The results show that the factors affecting the adsorption of lead followed the order of pH > SCTS addition > initial concentration of Pb²⁺ > rotate speed. The optimal adsorption of Pb²⁺could be reached with the pH of 2, SCTS addition of 10 g·L^-1, Pb²⁺ initial concentration of 50 mg·L^-1, and rotate speed of 130 r·min^-1, and the removal rate of Pb²⁺ reached 95.76%. The factors influencing the adsorption of cadmium followed the order of pH > initial concentration of Cd²⁺ > rotate speed > SCTS addition. The optimal adsorption of Cd²⁺ could be reached with the pH of 2, SCTS addition of 2.5 g·L^-1, Cd²⁺ initial concentration of 60 mg·L^-1, and rotate speed of 130 r·min^-1, and the removal rate of Cd²⁺ reached 96.08%. The composite adsorbent explores a new way for reutilization of sludge and provides a new method for wastewater treatment.

Key words: chitosan, composite adsorbent, cadmium, lead, wastewater, adsorption

中图分类号:

赵佐平, 段敏, 刘智峰, 汤波, 同延安. 壳聚糖活性污泥复合吸附剂处理铅、镉废水研究[J]. 生态与农村环境学报, 2017, 33(8): 730-736.

ZHAO Zuo-ping, DUAN Min, LIU Zhi-feng, TANG Bo, TONG Yan-an. Research on Adsorption Performance of Chitosan-Activated Sludge Composite Adsorbent to Cadmium and Lead in Wastewater[J]. Journal of Ecology and Rural Environment, 2017, 33(8): 730-736.

参考文献

[1] 孙艳芳,刘芸.壳聚糖的交联改性及其吸附铜和铅离子的研究[J].西安交通大学学报,2013,47(11):127-132.[SUN Yan-fang,LIU Yun.Adsorption of Pb(Ⅱ) and Cu(Ⅱ) Ions by Cross-Lonked Chitosan Beads[J].Journal of Xi'an Jiaotong University,2013,47(11):127-132.]
[2] ZHOU L M,WANG Y P,LIU Z R,et al.Characteristics of Equilibrium,Kinetics Studies for Adsorption of Hg(Ⅱ) and Cu(Ⅱ) and Ni(Ⅱ) Ions by Thiourea-Modified Magnetic Chitosan Microspheres[J].Journal of Hazardous materials,2009,161(2/3):995-1002.
[3] NGAH W S,FATINATHAN S.Pb(Ⅱ) Biosorption Using Chitosan and Chitosan Derivatives Beads:Equilibrium,Ion Exchange and Mechanism Studies[J].Journal of Environmental Sciences,2010,22(3):338-346.
[4] ROGERIO L,THIAGO G,BRUNO S,et al.Adsorption and Desorption of Cu(Ⅱ),Cd(Ⅱ) and Pb(Ⅱ) Ions Using Chitosan Crosslinked With Epichlorohydrin-Triphosphate as the Adsorbent[J].Journal of Hazardous Materials,2010,183(1):233-241.
[5] 王菲,杨国录,刘林双,等.城市污泥资源化利用现状及发展探讨[J].南水北调与水利科技,2013,11(2):99-103.[WANG Fei,YANG Guo-lu,LIU Lin-shuang,et al.Research on Development and Utilization of Municipal Sewage Sludge[J].South-to-North Water Transfers and Water Science & Technology,2013,11(2):99-103.]
[6] 王士龙,张虹,朱孔秀,等.用活性污泥处理含铅废水的试验研究[J].材料保护,2002,35(4):53-56.[WANG Shi-long,ZHANG Hong,ZHU Kong-xiu,et al.The Study of Activated Aludge Treatment of Wastewater Containing Lead[J].Materials Protection,2002,35(4):53-56.]
[7] 彭立凤.壳聚糖的制备及其在废水处理中的应用[J].化学世界,1999(4):8-11.[PENG Li-feng.The Preparation of Chitosan and Its Application in Waste Water Treatment[J].Chemical World,1999(4):8-11.]
[8] 敖晓奎,罗琳,关欣,等.废弃茶叶渣对铅离子的吸附研究[J].农业环境科学学报,2008,27(1):372-374.[AO Xiao-kui,LUO Lin,GUAN Xin,et al.Adsorption of Lead Ion by Waste Tea[J].Journal of Agro-Environment Science,2008,27(1):372-374.]
[9] 朱巨建,周衍波,张永利,等.壳聚糖的改性及在印染废水处理中的应用[J].生态环境学报,2016,25(1):112-117.[ZHU Ju-jian,ZHOU Yan-bo,ZHANG Yong-li,et al.Modificaton of Chitosan and Its Application in Wastewater Treatment[J].Ecology and Environmental Sciences,2016,25(1):112-117.]
[10] 孙胜玲,王爱勤.铅模板交联壳聚糖对Pb(Ⅱ)的吸附性能[J].中国环境科学,2005,25(2):192-195.[SUN Sheng-ling,WANG Ai-qin.Adsorption Properties of Pb(Ⅱ) Template Chitosan by Cross-Linked With Glutaraldehyde[J].China Environmental Science,2005,25(2):192-195.]
[11] SANDHYA B,TONNI A K.Study on Cr (VI) Removal From Contaminated Wastewater Using Natural Zeolite[J].Journal of Ion Exchange,2003,14:289-292.
[12] 郭敏杰,刘振,李梅.壳聚糖吸附重金属离子的研究进展[J].化工环保,2004,24(4):262-265.[GUO Min-jie,LIU Zhen,LI Mei.Research Progresses on Adsorbing Heavy Metal Ions With Chitosan[J].Environmental Protection of Chemical Industry,2004,24(4):262-265.]
[13] 李永明,于水利,唐玉霖.壳聚糖絮凝剂在水处理中的应用研究进展[J].水处理技术,2011,37(9):11-14.[LI Yong-ming,YU Shui-li,TANG Yu-lin.Research and Application of Chitosan and Its Derivatives in Water Treatment[J].Technology of Water Treatment,2011,37(9):11-14.]
[14] 孙昌梅,曲荣君,王春华,等.基于壳聚糖及其衍生物的金属离子吸附剂的研究进展[J].离子交换与吸附,2004,20(2):184-192.[SUN Chang-mei,QU Rong-jun,WANG Chun-hua,et al.Progress in Adsorbents for Metal Ions Based on Chitosan and Its Derivatives[J].Ion Exchange and Adsorption,2004,20(2):184-192.]
[15] 向文英,张志明.壳聚糖活性污泥复合吸附剂的制备研究[J].环境科学学报,2014,34(11):2792-2797.[XIANG Wen-ying,ZHANG Zhi-ming.Preparation of Composite Adsorbent With Chitosan and Activated Sludge[J].Acta Scientiae Circumstantiae,2014,34(11):2792-2797.]
[16] FABRIS R,CHOW C W,DRIKAS M.Evaluation of Chitosan as a Natural Coagulant for Drinking Water Treatment[J].Water Science & Technoloy,2010,61(8):2119-2128.
[17] 沈祥信,李小明,曾光明,等.活性污泥吸附重金属离子的研究进展[J].工业用水与废水,2006,37(4):7-11.[SHEN Xiang-xin,LI Xiao-ming,ZENG Guang-ming,et al.Development of Research on Adsorption of Heavy Metal Ions by Activated Sludge[J].Industrial Water & Wastewater,2006,37(4):7-11.]
[18] KATSUTOSHI I,YOSHIZUKA K,OHTO K.Adsorptive Separation of Some Metal Ions by Complexing Agent Types of Chemically Modified Chitosan[J].Analytica Chimica Acta,1999,388(1/2):209-218.
[19] 王林.EDTA-壳聚糖的制备及对Cd²⁺、Pb²⁺的吸附研究[D].广州:广东海洋大学,2013.[WANG Lin.Study on the Preparation of EDTA-Chitosan and Adsorption of Cd²⁺ and Pb²⁺[D].Guangzhou:Guangdong Ocean University,2013.]
[20] 程珊珊,杨锡洪,章超桦,等.壳聚糖对镉铅混合离子吸附作用的研究[J].现代食品科技,2011,27(3):257-261,274.[CHENG Shan-shan,YANG Xi-hong,ZHANG Chao-hua,et al.Adsorption of Mixed Cadmiun and Plumbum Ions by Chitosan[J].Modern Food Science and Technology,2011,27(3):257-261,274.]
[21] 杨家添,韦庆敏,谢秋季,等.花状BiOBr催化剂制备及对废水底物降解的光催化特性[J].生态与农村环境学报,2016,32(5):818-825.[YANG Jia-tian,WEI Qing-min,XIE Qiu-ji,et al.Preparation of Floriform BiOBr and Its Photocatalytic Characteristics in Degrding Wastewater Substrate[J].Journal of Ecology and Rural Environment,2016,32(5):818-825.]
[22] ALEXANDRE T P,MARCOS R G,ADRIANO V R,et al.Capacity of Adsorption of Pb²⁺ and Ni²⁺ From Queous Solutions by Chitosan Produced From Silkworm Chrysalides in Different Degrees of Deacetylation[J].Journal of Hazardous Materials,2007,147:139-147.
[23] 张艳雅,马启敏.壳聚糖改性吸附剂的制备及其吸附性能研究[J].中国海洋大学学报(自然科学版),2006,36(5):153-156.[ZHANG Yan-ya,MA Qi-min.Adsorbent Prepared From Modified Chitosan Derivatives and Study of Its Adsorption Behavior[J].Periodical of Ocean University of China,2006,36(5):153-156.]
[24] 王岚,王龙耀.生物吸附剂及其应用研究进展[J].天津化工,2006,20(5):5-8.[WANG Lan,WANG Long-yao.Progress of Biosorbent and Its Applications[J].Tianjin Chemical Industry,2006,20(5):5-8.]
[25] MOISSAVI G,BARIKBIN B.Biosorption of Chromium(VI) From Industrial Waste Water Onto Pistachio Hull Waste Bimass[J].Chemical Engineering Journal,2010,162(3):893-900.
[26] 姚瑞华,孟范平,张龙军,等.改性壳聚糖对重金属离子的吸附研究和应用进展[J].材料报道,2008,22(4):65-70.[YAO Rui-hua,MENG Fan-ping,ZHANG Long-jun,et al.Study and Application of Adsorption of Heavy Metal Ions by Modified Chitosan[J].Materials Review,2008,22(4):65-70.]

壳聚糖活性污泥复合吸附剂处理铅、镉废水研究

Research on Adsorption Performance of Chitosan-Activated Sludge Composite Adsorbent to Cadmium and Lead in Wastewater

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	曹俊敏, 李鑫, 徐德福. 骨炭对地下水中氟的吸附及去除能力研究[J]. 生态与农村环境学报, 2019, 35(8): 1064-1070.
[2]	邵爱云, 程德义, 代静玉, 杜琪雯, 杜超, 黄兆琴. 巯基改性稻壳炭对水中Cd²⁺的吸附特性[J]. 生态与农村环境学报, 2019, 35(8): 1071-1079.
[3]	常会庆, 朱晓辉, 郑彩杰, 焦常锋, 王启震, 吴杰. 颗粒无烟煤活性炭去除水体中低浓度磷酸盐研究[J]. 生态与农村环境学报, 2019, 35(8): 1058-1063.
[4]	王丽, 胡苗, 徐建军. 虾壳生物质炭对水体中Cr⁶⁺的吸附[J]. 生态与农村环境学报, 2019, 35(8): 1080-1088.
[5]	王恒煦, 刘泽平, 王志刚, 徐伟慧, 郭茹鑫. 3株芽孢杆菌在水稻根际定殖促生及其在土壤中的存活[J]. 生态与农村环境学报, 2019, 35(7): 892-899.
[6]	马洁晨, 汪新亮, 张学胜, 李玉成, 郑刘根, 王宁. 不同热解温度龙虾壳生物炭特征及对Zn²⁺的吸附机制[J]. 生态与农村环境学报, 2019, 35(7): 900-908.
[7]	干方群, 徐子昊, 杨一帆, 秦品珠, 唐荣, 杭小帅. 高岭土对畜禽废水中磷的净化效果及其费效分析[J]. 生态与农村环境学报, 2019, 35(6): 795-800.
[8]	王慧, 唐杉, 韩上, 李敏, 武际, 程文龙, 吴萍萍. 磷对镉离子在针铁矿及针铁矿-胡敏酸复合体表面吸附的影响[J]. 生态与农村环境学报, 2019, 35(5): 659-667.
[9]	解宇峰, 程德义, 石佳奇, 祝欣, 李志琳, 王磊. 高锰酸钾改性小麦秸秆吸附Cd²⁺的性能研究[J]. 生态与农村环境学报, 2019, 35(5): 668-674.
[10]	田雪, 周文君, 张正蕊, 李军娟, 高育慧. 不同时间下钝化剂对污染土壤中Cd和Pb的钝化效果[J]. 生态与农村环境学报, 2019, 35(4): 522-528.
[11]	彭鸥, 李丹阳, 刘寿涛, 罗海艳, 魏祥东, 叶长城, 刘孝利, 铁柏清, 陈文艳. 镉胁迫对水稻生长发育的影响及伤流液与稻米镉含量的相关性研究[J]. 生态与农村环境学报, 2019, 35(1): 76-82.
[12]	孟莉蓉, 俞浩丹, 杨婷婷, 尹微琴, 侯建华, 王圣森, 王小治. 改性豆饼生物质炭对铅的吸附特性[J]. 生态与农村环境学报, 2018, 34(7): 643-650.
[13]	黄荣, 徐应明, 黄青青, 谢忠雷, 尹秀玲, 秦旭. 不同氮磷钾肥对海泡石钝化修复镉污染土壤的稳定性研究[J]. 生态与农村环境学报, 2018, 34(6): 547-553.
[14]	汪婵娟, 熊治廷, 徐仲瑞, 刘荣相. 有色金属矿区植物根际耐镉菌的分离鉴定与镉吸附特性[J]. 生态与农村环境学报, 2018, 34(5): 448-455.
[15]	申磊, 荆延德, 孙小银, 郝郝, 曹永强. 动植物来源生物炭对水体中Cd²⁺的吸附特性[J]. 生态与农村环境学报, 2018, 34(4): 363-370.