生态与农村环境学报 ›› 2019, Vol. 35 ›› Issue (10): 1225-1231.doi: 10.19741/j.issn.1673-4831.2019.0147
张志伟1,2, 徐斌1, 张毅敏1,2, 巴翠翠1,2, 汤志凯1,2, 顾诗云1,2
收稿日期:
2019-03-12
出版日期:
2019-10-25
发布日期:
2019-10-23
通讯作者:
徐斌, 张毅敏
E-mail:xubinnies@163.com;zym7127@163.com
作者简介:
张志伟(1995-),男,安徽六安人,硕士生,主要从事膜分离与水处理研究。E-mail:252357395@qq.com
基金资助:
ZHANG Zhi-wei1,2, XU Bin1, ZHANG Yi-min1,2, BA Cui-cui1,2, TANG Zhi-kai1,2, GU Shi-yun1,2
Received:
2019-03-12
Online:
2019-10-25
Published:
2019-10-23
摘要: 氧化石墨烯(GO)复合膜基于良好的亲水性、丰富的官能团、较大的比表面积及化学稳定性等优异性能在膜分离领域备受关注。该文综述了GO复合膜的制备方法,包括真空过滤法、旋涂法、层层自组装法、掺杂法和共混法等,介绍了其在微污染水体和工业废水深度处理领域的研究进展,探讨了GO复合膜对污染物的分离机理,并对其在水处理领域的应用前景和今后的研究方向进行了展望。
中图分类号:
张志伟, 徐斌, 张毅敏, 巴翠翠, 汤志凯, 顾诗云. 氧化石墨烯复合膜在水处理中的应用研究进展与展望[J]. 生态与农村环境学报, 2019, 35(10): 1225-1231.
ZHANG Zhi-wei, XU Bin, ZHANG Yi-min, BA Cui-cui, TANG Zhi-kai, GU Shi-yun. Research Progress and Prospect of Graphene Oxide Modified Composite Membrane in Water Treatment.[J]. Journal of Ecology and Rural Environment, 2019, 35(10): 1225-1231.
[1] | PABBY A K,RIZVI S S H,REQUENA A M S.Handbook of Membrane Separations[M].New York,USA:CRC Press,2008:1184.DOI:10.1201/9781420009484. |
[2] | SUN M,LI J H.Graphene Oxide Membranes:Functional Structures,Preparation and Environmental Applications[J].Nano Today,2018,20:121-137. |
[3] | HUMMERS W S JR,OFFEMAN R E.Preparation of Graphitic Oxide[J].Journal of the American Chemical Society,1958,80(6):1339.DOI:10.1021/ja01539a017. |
[4] | LAI L F,CHEN L W,ZHAN D,et al.One-Step Synthesis of NH2-Graphene From in Situ Graphene-Oxide Reduction and Its Improved Electrochemical Properties[J].Carbon,2011,49(10):3250-3257. |
[5] | MARCANO D C,KOSYNKIN D V,BERLIN J M,et al.Improved Synthesis of Graphene Oxide[J].ACS Nano,2010,4(8):4806-4814. |
[6] | SHI J L,WU W F,XIA Y,et al.Confined Interfacial Polymerization of Polyamide-Graphene Oxide Composite Membranes for Water Desalination[J].Desalination,2018,441:77-86. |
[7] | ZHU J Y,TIAN M,HOU J W,et al.Surface Zwitterionic Functionalized Graphene Oxide for a Novel Loose Nanofiltration Membrane[J].Journal of Materials Chemistry A,2016,4(5):1980-1990. |
[8] | YU L,ZHANG Y T,ZHANG B,et al.Preparation and Characterization of HPEI-GO/PES Ultrafiltration Membrane With Antifouling and Antibacterial Properties[J].Journal of Membrane Science,2013,447:452-462. |
[9] | HOSSEINI M,AZAMAT J F,ERFAN-NIYA H.Improving the Performance of Water Desalination Through Ultra-Permeable Functionalized Nanoporous Graphene Oxide Membrane[J].Applied Surface Science,2018,427:1000-1008. |
[10] | LIU P Y,YAN T T,SHI L Y,et al.Graphene-Based Materials for Capacitive Deionization[J].Journal of Materials Chemistry A,2017,5(27):13907-13943. |
[11] | DUAN H Y,YAN T T,CHEN G R,et al.A Facile Strategy for the Fast Construction of Porous Graphene Frameworks and Their Enhanced Electrosorption Performance[J].Chemical Communications,2017,53(54):7465-7468. |
[12] | SURWADE S P,SMIRNOV S N,VLASSIOUK I V,et al.Water Desalination Using Nanoporous Single-Layer Graphene[J].Nature Nanotechnology,2015,10(5):459-464. |
[13] | JAIN T,RASERA B C,GUERRERO R J S,et al.Heterogeneous Sub-Continuum Ionic Transport in Statistically Isolated Graphene Nanopores[J].Nature Nanotechnology,2015,10(12):1053-1057. |
[14] | COHEN-TANUGI D,GROSSMAN J C.Mechanical Strength of Nanoporous Graphene as a Desalination Membrane[J].Nano Letters,2014,14(11):6171-6178. |
[15] | LIN L C,GROSSMAN J C.Atomistic Understandings of Reduced Graphene Oxide as an Ultrathin-Film Nanoporous Membrane for Separations[J].Nature Communications,2015,6:8335.DOI:10.1038/ncomms9335. |
[16] | KIDAMBI P R,BOUTILIER M S H,WANG L D,et al.Selective Nanoscale Mass Transport Across Atomically Thin Single Crystalline Graphene Membranes[J].Advanced Materials,2017,29(19):1605896.DOI:10.1002/adma.201605896. |
[17] | WANG L D,BOUTILIER M S H,KIDAMBI P R,et al.Fundamental Transport Mechanisms,Fabrication and Potential Applications of Nanoporous Atomically Thin Membranes[J].Nature Nanotechnology,2017,12(6):509-522. |
[18] | HUANG H B,MAO Y Y,YING Y L,et al.Salt Concentration,pH and Pressure Controlled Separation of Small Molecules Through Lamellar Graphene Oxide Membranes[J].Chemical Communications,2013,49(53):5963-5965. |
[19] | HUANG K,LIU G P,LOU Y Y,et al.A Graphene Oxide Membrane With Highly Selective Molecular Separation of Aqueous Organic Solution[J].Angewandte Chemie,2014,126(27):7049-7052. |
[20] | YOU Y,JIN X H,WEN X Y,et al.Application of Graphene Oxide Membranes for Removal of Natural Organic Matter From Water[J].Carbon,2018,129:415-419. |
[21] | DU Y C,HUANG L J,WANG Y X,et al.Recent Developments in Graphene-Based Polymer Composite Membranes:Preparation,Mass Transfer Mechanism,and Applications[J].Journal of Applied Polymer Science,2019,136(28):47761.DOI:10.1002/app.47761. |
[22] | SHAO L,CHENG X Q,WANG Z X,et al.Tuning the Performance of Polypyrrole-Based Solvent-Resistant Composite Nanofiltration Membranes by Optimizing Polymerization Conditions and Incorporating Graphene-Oxide[J].Journal of Membrane Science,2014,452:82-89. |
[23] | SANYAL O,LEE I.Recent Progress in the Applications of Layer-by-Layer Assembly to the Preparation of Nanostructured Ion-Rejecting Water Purification Membranes[J].Journal of Nanoscience and Nanotechnology,2014,14(3):2178-2189. |
[24] | HU M,MI B X.Enabling Graphene Oxide Nanosheets as Water Separation Membranes[J].Environmental Science & Technology,2013,47(8):3715-3723. |
[25] | CHAE H R,LEE J,LEE C H,et al.Graphene Oxide-Embedded Thin-Film Composite Reverse Osmosis Membrane With High Flux,Anti-Biofouling,and Chlorine Resistance[J].Journal of Membrane Science,2015,483:128-135. |
[26] | YIN J,ZHU G C,DENG B L.Graphene Oxide (GO) Enhanced Polyamide (PA) Thin-Film Nanocomposite (TFN) Membrane for Water Purification[J].Desalination,2016,379:93-101. |
[27] | LIU Q,XU G R.Graphene Oxide (GO) as Functional Material in Tailoring Polyamide Thin Film Composite (PA-TFC) Reverse Osmosis (RO) Membranes[J].Desalination,2016,394:162-175. |
[28] | ZHANG X,WANG Y,LIU Y F,et al.Preparation,Performances of PVDF/ZnO Hybrid Membranes and Their Applications in the Removal of Copper Ions[J].Applied Surface Science,2014,316(15):333-340. |
[29] | WANG Z H,YU H R,XIA J F,et al.Novel GO-Blended PVDF Ultrafiltration Membranes[J].Desalination,2012,299:50-54. |
[30] | ZHANG J G,XU Z,MAI W,et al.Improved Hydrophilicity,Permeability,Antifouling and Mechanical Performance of PVDF Composite Ultrafiltration Membranes Tailored by Oxidized Low-Dimensional Carbon Nanomaterials[J].Journal of Materials Chemistry A,2013,1(9):3101-3111. |
[31] | LI Z K,LANG W Z,MIAO W,et al.Preparation and Properties of PVDF/SiO2@GO Nanohybrid Membranes via Thermally Induced Phase Separation Method[J].Journal of Membrane Science,2016,511:151-161. |
[32] | 丁元利,洪志发,刘相革,等.骨架修饰有机-无机杂化二氧化硅膜的研究进展[J].材料导报,2014,28(增刊1):262-264,267.[DING Yuan-li,HONG Zhi-fa,LIU Xiang-ge,et al.A Review on the Backbone Modified Organic-Inorganic Hybrid Silica Membranes[J].Materials Review,2014,28(Suppl.1):262-264,267.] |
[33] | 马志刚,马聪,王亮,等.GO-ZnO共混改性PVDF膜的制备及抗污染性能[J].中国给水排水,2018,34(1):42-47.[MA Zhi-gang,MA Cong,WANG Liang,et al.Preparation and Antifouling Properties of GO/ZnO-Blended PVDF Membrane[J].China Water & Wastewater,2018,34(1):42-47.] |
[34] | 倪木子,夏圣骥,袁方竹,等.新型氧化石墨烯膜的制备及去除天然有机物研究[J].水处理技术,2016,42(8):40-47.[NI Mu-zi,XIA Sheng-ji,YUAN Fang-zhu,et al.Graphene Oxide Membranes Assembled for Removing Natural Organic Matter[J].Technology of Water Treatment,2016,42(8):40-47.] |
[35] | 冯雪婷,杨盛,文晨,等.Ag2CO3@PVDF/氧化石墨烯超滤膜及其分离性能[J].化工学报,2017,68(5):2169-2176.[FENG Xue-ting,YANG Sheng,WEN Chen,et al.Ag2CO3@PVDF/GO Ultrafiltration Membrane for Water Purification[J].CIESC Journal,2017,68(5):2169-2176.] |
[36] | ZHU Y,CHEN P P,NIE W Y,et al.Greatly Improved Oil-in-Water Emulsion Separation Properties of Graphene Oxide Membrane Upon Compositing With Halloysite Nanotubes[J].Water,Air,& Soil Pollution,2018,229(3):94.DOI:10.1007/s11270-018-3757-6. |
[37] | HO K C,TEOW Y H,ANG W L,et al.Novel GO/OMWCNTs Mixed-Matrix Membrane With Enhanced Antifouling Property for Palm Oil Mill Effluent Treatment[J].Separation and Purification Technology,2017,177:337-349. |
[38] | VIRAKA N B P,KANCHANAPALLY R,PEDRAZA F,et al.Bio-Conjugated CNT-Bridged 3D Porous Graphene Oxide Membrane for Highly Efficient Disinfection of Pathogenic Bacteria and Removal of Toxic Metals From Water[J].ACS Applied Materials & Interfaces,2015,7(34):19210-19218. |
[39] | CELIK E,PARK H,CHOI H,et al.Carbon Nanotube Blended Polyethersulfone Membranes for Fouling Control in Water Treatment[J].Water Research,2011,45(1):274-282. |
[40] | 刘立言,裴杨,龙明策,等.表面改性GOT/PVDF超滤膜的制备及对水中微污染物的去除[J].环境工程学报,2017,11(10):5381-5386.[LIU Li-yan,PEI Yang,LONG Ming-ce,et al.Fabrication of Surface Modified GOT/PVDF Ultrafiltration Membrane and Its Removal of Micro-Pollutants From Aqueous Solution[J].Chinese Journal of Environmental Engineering,2017,11(10):5381-5386.] |
[41] | VALLEJO W,RUEDA A,DÍAZ-URIBE C,et al.Photocatalytic Activity of Graphene Oxide-TiO2 Thin Films Sensitized by Natural Dyes Extracted From Bactris guineensis[J].Royal Society Open Science,2019,6(3):181824.DOI:10.1098/rsos.181824. |
[42] | LI T T,GAO Y,ZHOU J W,et al.A Membrane Modified With Nitrogen-Doped TiO2/Graphene Oxide for Improved Photocatalytic Performance[J].Applied Sciences,2019,9(5):855.DOI:10.3390/app9050855. |
[43] | 赵金琴,焦东,武书彬,等.氧化石墨烯膜应用于造纸废水深度处理的研究[J].造纸科学与技术,2017,36(3):79-85.[ZHAO Jin-qin,JIAO Dong,WU Shu-bin,et al.Study on the Advanced Treatment of Papermaking Wastewater by Graphene Oxide Ceramics Composite Membrane[J].Paper Science & Technology,2017,36(3):79-85.] |
[44] | GAO S J,QIN H L,LIU P P,et al.SWCNT-Intercalated GO Ultrathin Films for Ultrafast Separation of Molecules[J].Journal of Materials Chemistry A,2015,3(12):6649-6654. |
[45] | HOSSEINI M,AZAMAT J,ERFAN-NIYA H.Water Desalination Through Fluorine-Functionalized Nanoporous Graphene Oxide Membranes[J].Materials Chemistry and Physics,2019,223:277-286. |
[46] | BANDARA P C,NADRES E T,RODRIGUES D F.Use of Response Surface Methodology to Develop and Optimize the Composition of a Chitosan-Polyethyleneimine-Graphene Oxide Nanocomposite Membrane Coating to More Effectively Remove Cr(Ⅵ) and Cu(Ⅱ) From Water[J].ACS Applied Materials & Interfaces,2019,11(19):17784-17795. |
[47] | HAN Y,XU Z,GAO C.Ultrathin Graphene Nanofiltration Membrane for Water Purification[J].Advanced Functional Materials,2013,23(29):3693-3700. |
[48] | COHEN-TANUGI D,GROSSMAN J C.Water Desalination Across Nanoporous Graphene[J].Nano Letters,2012,12(7):3602-3608. |
[49] | MI B.Graphene Oxide Membranes for Ionic and Molecular Sieving[J].Science,2014,343(6172):740-742. |
[50] | ZHAO G X,LI J X,REN X M,et al.Few-Layered Graphene Oxide Nanosheets as Superior Sorbents or Bents for Heavy Metal Ion Pollution Management[J].Environmental Science & Technology,2011,45(24):10454-10462. |
[51] | CHEN L,SHI G S,SHEN J,et al.Ion Sieving in Graphene Oxide Membranes via Cationic Control of Interlayer Spacing[J].Nature,2017,550(7676):380-383. |
[52] | XI Y H,LIU Z,JI J Y,et al.Graphene-Based Membranes With Uniform 2D Nanochannels for Precise Sieving of Mono-/Multi-Valent Metal Ions[J].Journal of Membrane Science,2018,550:208-218. |
[53] | SUN P Z,ZHU M,WANG K L,et al.Selective Ion Penetration of Graphene Oxide Membranes[J].ACS Nano,2013,7(1):428-437. |
[54] | ZHANG L N,CHEN B L,GHAFFAR A,et al.Nanocomposite Membrane With Polyethylenimine-Grafted Graphene Oxide as a Novel Additive to Enhance Pollutant Filtration Performance[J].Environmental Science & Technology,2018,52(10):5920-5930. |
[55] | NAEEM H,AJMAL M,MUNTHA S,et al.Synthesis and Characterization of Graphene Oxide Sheets Integrated With Gold Nanoparticles and Their Applications to Adsorptive Removal and Catalytic Reduction of Water Contaminants[J].RSC Advances,2018,8(7):3599-3610. |
[56] | AYYARU S,AHN Y H.Application of Sulfonic Acid Group Functionalized Graphene Oxide to Improve Hydrophilicity,Permeability,and Antifouling of PVDF Nanocomposite Ultrafiltration Membranes[J].Journal of Membrane Science,2017,525(1):210-219. |
[57] | WEI Y B,ZHU Y X,JIANG Y J.Photocatalytic Self-Cleaning Carbon Nitride Nanotube Intercalated Reduced Graphene Oxide Membranes for Enhanced Water Purification[J].Chemical Engineering Journal,2019,356:915-925. |
[58] | ZHANG Q,CHEN S,FAN X F,et al.A Multifunctional Graphene-Based Nanofiltration Membrane Under Photo-Assistance for Enhanced Water Treatment Based on Layer-by-Layer Sieving[J].Applied Catalysis B:Environmental,2018,224:204-213. |
[59] | ALMEIDA N A,MARTINS P M,TEIXEIRA S,et al.TiO2/Graphene Oxide Immobilized in P(VDF-TrFE) Electrospun Membranes With Enhanced Visible-Light-Induced Photocatalytic Performance[J].Journal of Materials Science,2016,51(14):6974-6986. |
[60] | YU Z X,MIN X,LI F,et al.A Mussel-Inspired Method to Fabricate a Novel Reduced Graphene Oxide/Bi12O17Cl2 Composites Membrane for Catalytic Degradation and Oil/Water Separation[J].Polymers for Advanced Technologies,2019,30(1):101-109. |
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