生态与农村环境学报 ›› 2007, Vol. 23 ›› Issue (1): 40-42.doi: CNKI:SUN:NCST.0.2007-01-008

• 论文 • 上一篇    下一篇

三峡库区消落区紫色土对重金属的吸附特征

丁武泉, 包兵, 李航, 宋仲容   

  1. 重庆文理学院化学与环境科学系
  • 收稿日期:2006-08-28 出版日期:2007-01-25 发布日期:2011-05-09
  • 通讯作者: 李航 西南大学资源环境学院
  • 作者简介:丁武泉(1982-),男,江西临川人,助教,主要从事土壤化学与环境污染防治教学与研究。
  • 基金资助:

    中国科学院土壤与农业可持续发展国家重点实验室开放基金(035108);重庆文理学院校级课题资助

Heavy Metal Adsorption Characteristics of Purple Soil in Water-Level-Fluctuating Zone of the Three-Gorge Reservoir Region

DING  Wu-Quan, BAO  Bing, LI  Hang, SONG  Zhong-Rong   

  1. Department of Chemistry and Environmental Science,Chongqing University of Arts and Science
  • Received:2006-08-28 Online:2007-01-25 Published:2011-05-09
  • Contact: LI Hang College of Resources and Environment,Southwest University

摘要: 为了解三峡库区消落区紫色土对重金属的吸附特点,采用振荡平衡方法研究石灰性、中性和酸性3种紫色土对Pb2+、Cu2+、Zn2+和Cd2+的吸附特征,并比较不同环境条件对紫色土吸附重金属的影响。结果表明:(1)一定pH条件下,同种土壤对4种重金属离子的吸附能力依次为Pb2+>Cu2+>Cd2+≈Zn2+;(2)在一定pH条件下,石灰性紫色土、中性紫色土、酸性紫色土对同种重金属离子的吸附强度依次降低,与其表面电荷密度的大小相一致;(3)石灰性紫色土、中性紫色土和酸性紫色土表面对Pb2+和Cu2+的吸附以静电和专性方式共存,其中对Pb2+的专性吸附比例分别约为56%、67%和50%;而对Zn2+和Cd2+绝大多数情况下产生静电吸附。

关键词: 重金属, 吸附, 紫色土, 三峡库区

Abstract: In order to understand heavy metal(including Pb2+,Cu2+,Zn2+,Cd2+) adsorption characteristics of purple soil in the water-level-fluctuating zone of the Three-Gorge reservoir region,an experiment was carried out to study heavy metal adsorption behavior of acidic,neutral and calcareous purplish soils under different conditions with the batch sorption method.Results show that(1)with a certain pH,a soil adsorbed heavy metals with strength varying in the order of Pb2+>Cu2+>Cd2+≈Zn2+;(2)with a certain pH,the three soils absorbed the same heavy metal with strength in the order of calcareous purplish soils>neutral>acidic,which is in line with the order in surface charge density;(3)Pb2+and Cu2+ adsorption on the surface of the three soils existed in both static and specific patterns.The specific pattern accounted for 56%,67% and 50% respectively,in the case of Pb2+.Static pattern was in dominancy in the case of Zn2+and Cd2+

Key words: heavy metal, adsorption, purple soil, Three-Gorge reservoir region

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