条浒苔与玉米秸秆热解特性及所制生物炭性质对比

doi:10.11934/j.issn.1673-4831.2016.05.025

生态与农村环境学报 ›› 2016, Vol. 32 ›› Issue (5): 847-851.doi: 10.11934/j.issn.1673-4831.2016.05.025

条浒苔与玉米秸秆热解特性及所制生物炭性质对比

张兴源¹, 单瑞峰², 孙小银², 刘飞², 王萍², 张子彤¹, 张振北¹

1. 曲阜师范大学地理与旅游学院, 山东日照 276826;
2. 南四湖湿地生态与环境保护山东省高校重点实验室, 山东日照 276826

收稿日期:2016-01-04 出版日期:2016-09-25 发布日期:2016-10-08
通讯作者: 单瑞峰,E-mail:ruifeng_shan@163.com E-mail:ruifeng_shan@163.com
作者简介:张兴源(1993-),男,山东济南人,本科生,主要从事自然地理与资源环境方面的研究。E-mail:346609778@qq.com
基金资助:
山东省优秀中青年科学家科研奖励基金（BS2013NY009）；山东省高等学校科技计划（J13LF02）；国家自然科学基金（41501542）

Pyrolytic Features of Enteromorpha compressa and Zea mays and Comparison Between Their Biochar Products in Property

ZHANG Xing-yuan¹, SHAN Rui-feng², SUN Xiao-yin², LIU Fei², WANG Ping², ZHANG Zi-tong¹, ZHANG Zhen-bei¹

1. College of Geography and Tourism, Qufu Normal University, Rizhao 276826, China;
2. Key Laboratory of Wetland Ecology and Environmental Protection in Nansi Lake(Shandong Province), Rizhao 276826, China

Received:2016-01-04 Online:2016-09-25 Published:2016-10-08

摘要/Abstract

摘要：

为探讨沿海绿潮藻类浒苔的资源化利用潜力，应用热重-差示扫描量热技术（TG-DSC）对条浒苔（Enteromorpha compressa）和玉米（Zea mays）秸秆的热解特性及其在不同温度下制成的生物炭的性质进行对比。结果表明，条浒苔与玉米秸秆热解特性有较大差异，条浒苔热稳定性较差，热解反应温度低，制备相同热解温度的生物炭需热量较少。对2种材料所制备生物炭的性质分析表明，条浒苔基生物炭的w（碳）为33.47%~37.86%，仅为玉米秸秆基生物炭含量的49.07%~65.41%，其芳香化合程度、比表面积均低于相同热解温度下玉米秸秆基生物炭；但条浒苔基生物炭灰分和氮含量却远高于玉米秸秆基生物炭，分别是玉米秸秆基生物炭的3.83~4.53和6.39~30.33倍。

关键词: 条浒苔, 玉米秸秆, 热解, 生物炭

Abstract:

In order to explore potential of the algae to be used as resource, researches were done to determine pyrolytic feature of algae(Enteromorpha compressa) and cornstalk(Zea mays) with the technology of differential scanning calorimetry & thermo-gravimetric analysis (TG-DSC)and compare their pyrolysis products of biochar under different temperatures (350, 500 and 650 ℃) in property. Results show that the two materials differed sharply in pyrolytic feature. The algae are quite low in thermo-stability and pyrolytic reaction temperature, so they do not need so much heat as cornstalk does to get pyrolyzed into biochars at the same set temperature. Analysis of properties of the biochars prepared out of the algae and cornstalk shows that the biochar of algae was 33.47%-37.86% in carbon content, equaling to 49.07%-65.41% of the carbon content in the biochar of cornstalk, and also lower in specific surface area and aromatization degree than the biochar of cornstalk. However, the former was far too much higher than the latter in ash content and nitrogen content or 3.83-4.53 and 3.38-30.33 times as high as the latter.

Key words: Enteromorpha compressa, Zea mays, pyrolysis, biochar

中图分类号:

X712
X714

张兴源, 单瑞峰, 孙小银, 刘飞, 王萍, 张子彤, 张振北. 条浒苔与玉米秸秆热解特性及所制生物炭性质对比[J]. 生态与农村环境学报, 2016, 32(5): 847-851.

ZHANG Xing-yuan, SHAN Rui-feng, SUN Xiao-yin, LIU Fei, WANG Ping, ZHANG Zi-tong, ZHANG Zhen-bei. Pyrolytic Features of Enteromorpha compressa and Zea mays and Comparison Between Their Biochar Products in Property[J]. Journal of Ecology and Rural Environment, 2016, 32(5): 847-851.

参考文献

[1] 高嵩,范士亮,韩秀荣,等.浒苔绿潮与南黄海近岸海域水质的关系[J].中国环境科学,2014,34(1):213-218.
[2] 秦搏,常青,陈四清,等.饲料中浒苔添加量以及处理方法对幼刺参生长、消化率、消化酶和非特异性免疫酶的影响[J].水产学报,2015,39(4):547-556.
[3] 刘天红,吴志宏,王颖,等.浒苔作为仿刺参幼参植物饲料源的可行性研究[J].水产科学,2013,32(10):597-600.
[4] 赵明,陈建美,蔡葵,等.浒苔堆肥化处理及对大白菜产量和品质的影响[J].中国土壤与肥料,2010,38(2):66-70.
[5] 李银平,王进,于源,等.浒苔生物有机肥的制备及其对樱桃萝卜品质影响的研究[J].食品工业科技,2013,34(24):120-124.
[6] 王爽,姜秀民,王谦,等.不同工况下条浒苔的快速热裂解制取生物油试验研究[J].热能动力工程,2013,28(2):202-222.
[7] 褚军,薛建辉,金梅娟,等.生物炭对农业面源污染氮、磷流失的影响研究进展[J].生态与农村环境学报,2014,30(4):409-415.
[8] SHARMA A,PAREEK V,ZHANG D.Biomass Pyrolysis:A Review of Modelling,Process Parameters and Catalytic Studies[J].Renewable and Sustainable Energy Reviews,2015,50(10):1081-1096.
[9] COLLARD F,BLIN J.A Review on Pyrolysis of Biomass Constituents:Mechanisms and Composition of The Products Obtained From the Conversion of Cellulose,Hemicelluloses and Lignin[J].Renewable and Sustainable Energy Reviews,2014,38(10):594-608. 李祯,王爽,徐姗楠,等.大型海藻浒苔热解特性与动力学研究[J].生物技术通报,2007,23(3):159-164.
[11] 赵辉,闫华晓,刘明,等.Al₂O₃催化剂对海洋生物质热解特性的影响[J].中国生物工程杂志,2010,30(8):37-41.
[12] 王爽,王谦,徐姗楠,等.海藻热解生物油的成分分析[J].农业工程学报,2013,29(17):204-211.
[13] SUGANYA T,GANDHI N,RENGANATHAN S.Production of Algal Biodiesel From Marine Macroalgae Enteromorpha compressa by Two Step Process:Optimization and Kinetic Study[J].Bioresource Technology,2013,128(3):392-400.
[14] KIM B,LEE H,PARK S,et al.Removal of Cu²⁺ by Biochars Derived From Green Macroalgae[J].Environmental Science and Pollution Research,2016,23(2):985-994.
[15] 王金主,王元秀,李峰,等.玉米秸秆中纤维素、半纤维素和木质素的测定[J].山东食品发酵,2010,158(3):44-47.
[16] XIAO X,CHEN B,ZHU L.Transformation,Morphology,and Dissolution of Silicon and Carbon in Rice Straw-Derived Biochars Under Different Pyrolytic Temperatures[J].Environmental Science and Technology,2014,48(6):3411-3419.
[17] GB/T 12496.7-1999,木质活性炭试验方法pH值的测定[S].
[18] 王爽.海藻生物质热解与燃烧的试验与机理研究[D].上海:上海交通大学,2010.
[19] 赵辉.大型海藻生物质热解动力学及热解液化工艺研究[D].北京:中国科学院研究生院(海洋研究所),2011.
[20] WU W,YANG M,FENG Q,et al.Chemical Characterization of Rice Straw-Derived Biochar for Soil Amendment[J].Biomass and Bioenergy,2012,47(12):268-276.

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条浒苔与玉米秸秆热解特性及所制生物炭性质对比

Pyrolytic Features of Enteromorpha compressa and Zea mays and Comparison Between Their Biochar Products in Property

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