我国大气VOCs的监测技术和污染特征研究进展

doi:10.11934/j.issn.1673-4831.2018.02.003

摘要/Abstract

摘要：

近年来，挥发性有机物（VOCs）作为光化学烟雾的前体物、灰霾天气形成的关键因素，引起国内外学者的广泛关注。该研究综述了我国大气VOCs的源与汇、监测技术和污染特征。首先概述了大气VOCs的源与汇，内容包括我国VOCs的自然源、人为源及主要的去除途径。然后讨论了国内外VOCs的监测技术，分析总结了我国现有的相关环境管理标准与技术规范。重点对我国近几年典型城市大气中VOCs的污染特征进行了归纳和对比，从检出VOCs种类、浓度释放水平和释放来源方面分析了各地区VOCs的污染水平，为大气环境的保护及污染防治提供科学依据。最后，在总结现有研究进展的基础上，提出了现阶段研究中存在的问题，展望了未来研究的主要方向。

关键词: 大气, 挥发性有机物, 源与汇, 监测技术, 污染特征

Abstract:

In recent years, volatile organic compounds (VOCs) of precursor of photochemical smog and the key factors of the formation of hazy weather have aroused extensive concerns among scholars both at home and abroad. This is a review retrospecting and summarizing researches on source and sink, monitoring technology and pollution characteristics of atmospheric VOCs, in China. The review began with generalizing the source and sink of VOCs, including natural and anthropogenic sources of VOCs and main paths of removing the substances. Then the review went on discussing VOCs monitoring techniques used at home and abroad, analyzing and summarizing existing relevant environmental management standards and technical specifications in China, and collating and comparing VOCs pollution characteristics in typical urban atmospheres in recent years. From the aspects of species of VOCs detected, their concentration release levels and sources of releases, atmospheric VOCs pollution levels of various regions were evaluated, providing certain scientific basis for protection and pollution prevention of the atmospheric environment. In the end, based on the summarization of the current research progresses, some main problems existing in the current studies are pointed out and future directions and development are prospected.

Key words: atmosphere, VOCs, source and sink, monitoring technique, pollution characteristics

中图分类号:

韩彩云, 赵欣, 单艳红, 张晓雨, 殷堂兵, 张春雷, 林玉锁. 我国大气VOCs的监测技术和污染特征研究进展[J]. 生态与农村环境学报, 2018, 34(2): 114-123.

HAN Cai-yun, ZHAO Xin, SHAN Yan-hong, ZHANG Xiao-yu, YIN Tang-bing, ZHANG Chun-lei, Lin Yu-suo. A Review of Researches on Atmospheric VOCs Monitoring Technique and Pollution Characteristics in China[J]. Journal of Ecology and Rural Environment, 2018, 34(2): 114-123.

参考文献

[1] GB 50325-2010,民用建筑工程室内环境污染控制规范[S].[GB 50325-2010,Code for Indoor Environmental Pollution Control of Civil Building Engineering[S].]
[2] 邵敏,董东.我国大气挥发性有机物污染与控制[J].环境保护,2013,41(5):25-28.[SHAO Min,DONG Dong.Pollution and Control of Atmospheric Volatile Organic Compounds in China[J].Environmental Protection,2013,41(5):25-28.]
[3] KALOGRIDIS C,GROS V,SARDA-ESTEVE R,et al.Concentrations and Fluxes of Isoprene and Oxygenated VOCs at a French Mediterranean Oak Forest[J].Atmospheric Chemistry and Physics,2014,14:10085-10102.
[4] KLIMONT Z,STREETS D G,GUPTA S,et al.Anthropogenic Emissions of Non-Methane Volatile Organic Compounds in China[J].Atmospheric Environment,2002,36(8):1309-1322.
[5] WU R R,XIE S D.Spatial Distribution of Ozone Formation in China Derived From Emissions of Speciated Volatile Organic Compounds[J].Environmental Science & Technology,2017,51(5):2574-2583.
[6] LI J L,ZHANG M G,WU F K,et al.Assessment of the Impacts of Aromatic VOC Emissions and Yields of SOA on SOA Concentrations With the Air Quality Model RAMS-CMAQ[J].Atmospheric Environment,2017,158:105-115.
[7] YOU Z Q,ZHU Y,JANG C,et al.Response Surface Modeling-Based Source Contribution Analysis and VOC Emission Control Policy Assessment in a Typical Ozone-Polluted Urban Shunde,China[J].Journal of Environmental Sciences,2017,51:294-304.
[8] WU R R,LI J,HAO Y F,et al.Evolution Process and Sources of Ambient Volatile Organic Compounds During a Severe Haze Event in Beijing,China[J].Science of the Total Environment,2016,560/561:62-72.
[9] ZHOU J,YOU Y,BAI Z P,et al.Health Risk Assessment of Personal Inhalation Exposure to Volatile Organic Compounds in Tianjin,China[J].Science of the Total Environment,2011,409(3):452-459.
[10] 莫梓伟,邵敏,陆思华.中国挥发性有机物(VOCs)排放源成分谱研究进展[J].环境科学学报,2014,34(9):2179-2189.[MO Zi-wei,SHAO Min,LU Si-hua.Review on Volatile Organic Compounds (VOCs) Source Profiles Measured in China[J].Acta Scientiae Circumstantiae,2014,34(9):2179-2189.]
[11] 杨新兴,李世莲,尉鹏,等.环境中的VOCs及其危害[J].前沿科学,2013,7(4):21-35.[YANG Xin-xing,LI Shi-lian,WEI Peng,et al.Volatile Organic Compounds in the Environment and Their Harms[J].Frontier Science,2013,7(4):21-35.]
[12] HAN L,QIAN L B,YAN J C,et al.A Comparison of Risk Modeling Tools and a Case Study for Human Health Risk Assessment of Volatile Organic Compounds in Contaminated Groundwater[J].Environmental Science and Pollution Research,2016,23(2):1234-1245.
[13] WANG C Z,SU Y,LI D,et al.Analysis of Volatile Organic Compounds From Dendranthema indicum var.aromaticumby Headspace Gas Chromatography-Mass Spectrometry and Accurate Mass Measurement[J].Analytical Letters,2010,43(15):2297-2310.
[14] ZHANG H,LI H,ZHANG Q Z,et al.Atmospheric Volatile Organic Compounds in a Typical Urban Area of Beijing:Pollution Characterization,Health Risk Assessment and Source Apportionment[J].Atmosphere,2017,8(3):61.
[15] 王红丽.上海市大气挥发性有机物化学消耗与臭氧生成的关系[J].环境科学,2015,36(9):3159-3167.[WANG Hong-li.Chemical Loss of Volatile Organic Compounds and Its Impact on the Formation of Ozone in Shanghai[J].Environmental Science,2015,36(9):3159-3167.]
[16] 安俊琳,朱彬,王红磊,等.南京北郊大气VOCs变化特征及来源解析[J].环境科学,2014,35(12):4454-4464.[AN Jun-lin,ZHU Bin,WANG Hong-lei,et al.Characteristics and Source Apportionment of Volatile Organic Compounds (VOCs) in the Northern Suburb of Nanjing[J].Environmental Science,2014,35(12):4454-4464.]
[17] WU R R,LI J,HAO Y F,et al.Evolution Process and Sources of Ambient Volatile Organic Compounds During a Severe Haze Event in Beijing,China[J].Science of the Total Environment,2016,560/561:62-72.
[18] LI L Y,XIE S D,ZENG L M,et al.Characteristics of Volatile Organic Compounds and Their Role in Ground-Level Ozone Formation in the Beijing-Tianjin-Hebei Region,China[J].Atmospheric Environment,2015,113:247-254.
[19] AN J L,WANG J X,ZHANG Y X,et al.Source Apportionment of Volatile Organic Compounds in an Urban Environment at the Yangtze River Delta,China[J].Archives of Environmental Contamination and Toxicology,2017,72(3):335-348.
[20] AN J L,WANG Y S,WU F K,et al.Characterizations of Volatile Organic Compounds During High Ozone Episodes in Beijing,China[J].Environmental Monitoring and Assessment,2012,184(4):1879-1889.
[21] 魏巍,王书肖,郝吉明.中国人为源VOC排放清单不确定性研究[J].环境科学,2011,32(2):305-312.[WEI Wei,WANG Shu-xiao,HAO Ji-ming.Uncertainty Analysis of Emission Inventory for Volatile Organic Compounds From Anthropogenic Sources in China.[J].Environmental Science,2011,32(2):305-312.]
[22] WEI W,WANG S X,CHATANI S,et al.Emission and Speciation of Non-Methane Volatile Organic Compounds From Anthropogenic Sources in China[J].Atmospheric Environment,2008,42(20):4976-4988.
[23] ZHENG J Y,ZHENG Z Y,YU Y F,et al.Temporal,Spatial Characteristics and Uncertainty of Biogenic VOC Emissions in the Pearl River Delta Region,China[J].Atmospheric Environment,2010,44(16):1960-1969.
[24] WEI W,WANG S X,HAO J M,et al.Projection of Anthropogenic Volatile Organic Compounds (VOCs) Emissions in China for the Period 2010-2020[J].Atmospheric Environment,2011,45(38):6863-6871.
[25] KANSAL A.Sources and Reactivity of NMHCs and VOCs in the Atmosphere:A Review[J].Journal of Hazardous Materials,2009,166(1):17-26.
[26] GUENTHER A,ZIMMERMAN P,KLINGER L,et al.Estimates of Regional Natural Volatile Organic Compound Fluxes From Enclosure and Ambient Measurements[J].Journal of Geophysical Research:Atmospheres,1996,101(D1):1345-1359.
[27] GUENTHER A,GERON C,PIERCE T,et al.Natural Emissions of Non-Methane Volatile Organic Compounds; Carbon Monoxide,and Oxides of Nitrogen From North America[J].Atmospheric Environment,2000,34(12/13/14):2205-2230.
[28] LI L Y,CHEN Y,XIE S D.Spatio-Temporal Variation of Biogenic Volatile Organic Compounds Emissions in China[J].Environmental Pollution,2013,182:157-168.
[29] KIM H J,TAKATA K,TANAKA K,et al.Regional Climatic Effects According to Different EstimationsofBiogenicVolatileOrganic Compounds During the Asian Summer Monsoon[J].Asia-Pacific Journal of Atmospheric Sciences,2014,50(4):423-435.
[30] LEE K H,KIM H C,HU C G.A Study on the Estimation of BVOCs Emission in Jeju Island (2):Emission Characteristic and Situation[J].Journal of Environmental Science International,2015,24(2):207-219.
[31] KIM J C,KIM K J,KIM D S,et al.Seasonal Variations of Monoterpene Emissions From Coniferous Trees of Different Ages in Korea[J].Chemosphere,2005,59(11):1685-1696.
[32] PEÑUELAS J,LLUSIAÀ J.Plant VOC Emissions:Making Use of the Unavoidable[J].Trends in Ecology & Evolution,2004,19(8):402-404.
[33] PINTO D M,BLANDE J D,NYKÄNEN R,et al.Ozone Degrades Common Herbivore-Induced Plant Volatiles:Does This Affect Herbivore Prey Location by Predators and Parasitoids?[J].Journal of Chemical Ecology,2007,33(4):683-694.
[34] HOLOPAINEN J K,GERSHENZON J.Multiple Stress Factors and the Emission of Plant VOCs[J].Trends in Plant Science,2010,15(3):176-184.
[35] TERMONIA A,TERMONIA M.Characterisation and On-Site Monitoring of Odorous Organic Compounds in the Environment of a Landfill Site[J].International Journal of Environmental Ananlytical Chemistry,1999,73(1):43-57.
[36] MILLS W B,LEW C S,LOH J Y.Predictions of Potential Human Health and Ecological Risks From Power Plant Discharges of Totalresidual Chlorineand Chloro Form Into Rivers[J].Environmental Science & Technology,1998,32(14):2162-2171.
[37] JAARS K,BEUKES J P,VAN ZYL P G,et al.Ambient Aromatic Hydrocarbon Measurements at Welgegund,South Africa[J].Atmospheric Chemistry and Physics,2014,14(13):7075-7089.
[38] WEI W,CHENG S Y,LI G H,et al.Characteristics of Volatile Organic Compounds (VOCs) Emitted From a Petroleum Refinery in Beijing,China[J].Atmospheric Environment,2014,89:358-366.
[39] FAUSER P,ⅢERUP J B.Danish Emission Inventory for Solvents Used in Industries and Households[J].Atmospheric Environment,2008,42(34):7947-7953.
[40] YUAN B,SHAO M,LU S H,et al.Source Profiles of Volatile Organic Compounds Associated With Solvent Use in Beijing,China[J].Atmospheric Environment,2010,44(15):1919-1926.
[41] LOBERT J M,KEENE W C,LOGAN J A,et al.Global Chlorine Emissions from Biomass Burning:Reactive Chlorine Emissions Inventory[J].Journal of Geophysical Research:Atmospheres,1999,104(D7):8373-8389.
[42] SHARMA S,GOEL A,GUPTA D,et al.Emission Inventory of Non-Methane Volatile Organic Compounds From Anthropogenic Sources in India[J].Atmospheric Environment,2015,102:209-219.
[43] ZHANG Y S,SHAO M,LIN Y,et al.Emission Inventory of Carbonaceous Pollutants From Biomass Burning in the Pearl River Delta Region,China[J].Atmospheric Environment,2013,76:189-199.
[44] WANG H L,LOU S R,HUANG C,et al.Source Profiles of Volatile Organic Compounds From Biomass Burning in Yangtze River Delta,China[J].Aerosol and Air Quality Research,2014,14:818-828.
[45] 陆思华,白郁华,张光山,等.大气中挥发性有机化合物(VOCs)的人为来源研究[J].环境科学学报,2006,26(5):757-763.[LU Si-hua,BAI Yu-hua,ZHANG Guang-shan,et al.Source Apportionment of Anthropogenic Emissions of Volatile Organic Compounds[J].Acta Scientiae Circumstantiae,2006,26(5):757-763.]
[46] ZHANG Q,YUAN B,SHAO M Z,et al.Variations of Ground-Level O₃ and Its Precursors in Beijing in Summertime Between 2005 and 2011[J].Atmospheric Chemistry and Physics,2014,14(12):6089-6101.
[47] WANG M,SHAO M,CHEN W,et al.Trends of Non-Methane Hydrocarbons (NMHC) Emissions in Beijing during 2002-2013[J].Atmospheric Chemistry and Physics,2015,15:1489-1502.
[48] LIU Y,SHAO M,FU L L,et al.Source Profiles of Volatile Organic Compounds (VOCs) Measured in China:Part Ⅰ[J].Atmospheric Environment,2008,42(25):6247-6260.
[49] 唐孝炎.大气环境化学[M].北京:高等教育出版社,1990.[TANG Xiao-yan.Atmospheric Environmental Chemistry[M].Beijing:Higher Education Press,1990.]
[50] JENKIN M E,SAUNDERS S M,WAGNER V,et al.Protocol for the Development of the Master Chemical Mechanism,MCM v3(Part B):Tropospheric Degradation of Aromatic Volatile Organic Compounds[J].Atmospheric Chemistry and Physics,2003,3(1):181-193.
[51] LEWIS A C,HOPKINS J R,CARPENTER L J,et al.Sources and Sinks of Acetone,Methanol,and Acetaldehyde in North Atlantic Marine Air[J].Atmospheric Chemistry and Physics,2005,5(7):1963-1974.
[52] FORNARO A,GUTZ I G R.Wet Deposition and Related Atmospheric Chemistry in the Sao Paulo Metropolis,Brazil:Part 2:Contribution of Formic and Acetic Acids[J].Atmospheric Environment,2003,37(1):117-128.
[53] DOSKEY P V,KOTAMARTHI V R,FUKUI Y,et al.Air-Surface Exchange of Peroxyacetyl Nitrate at a Grassland Site[J].Journal of geophysical Research Atmospheres,2004,109(D10):D10310.
[54] KARL T,HARLEY P,EMMONS L,et al.Efficient Atmospheric Cleansing of Oxidized Organic Trace Gases by Vegetation[J].Science,2010,330(6005):816-819.
[55] COUSINS I T,MACKAY D.Gas-Particle Partitioning of Organic Compounds and Its Interpretation Using Relative Solubilities[J].Environmental Science & Technology,2001,35(4):643-647.
[56] CLAEYS M,WANG W,ION A C,et al.Formation of Secondary Organic Aerosols From Isoprene and Its Gas-Phase Oxidation Products Through Reaction With Hydrogen Peroxide[J].Atmospheric Environment,2004,38(25):4093-4098.
[57] KUHN U,ROTTENBERGER S,BIESENTHAL T,et al.Exchange of Short-Chain Monocarboxylic Acids by Vegetation at A Remote Tropical Forest Site in Amazonia[J].Journal of Geophysical Research:Atmospheres,2002,107(D20):8069.
[58] HUTTE R S,WILLIAMS E J,STAEHELIN J,et al.Chromatographic Analysis of Organic Compounds in the Atmosphere[J].Journal of Chromatography A,1984,302:173-179.
[59] JANG C H,KIM Y H,KIM K H.Effective Carbon Number (ECN)-Based Evaluation of GC-FID Sensitivity and Split Ratio in the Analysis of Gaseous VOC:Comparison Between SPME and Direct Injection Method[J].Journal of Odor and Indoor Environment,2013,12(1):17-26.
[60] ZHANG Y L,WANG X M,SIMPSON I J,et al.Ambient CFCs and HCFC-22 Observed Concurrently at 84 Sites in the Pearl River Delta Region During the 2008-2009 Grid Studies[J].Journal of Geophysical Research:Atmospheres,2014,119(12):7699-7717.
[61] LIU K K,QUAN J N,MU Y J,et al.Aircraft Measurements of BTEX Compounds Around Beijing City[J].Atmospheric Environment,2013,73:11-15.
[62] LIU Y,SHAO M,ZHANG J,et al.Distributions and Source Apportionment of Ambient Volatile Organic Compounds in Beijing City,China[J].Journal of Environmental Science and Health:Part A:Toxic/Hazardous Substances & Environmental Engineering,2005,40(10):1843-1860.
[63] RAS M R,BORRULL F,MARCÉ R M.Sampling and Preconcentration Techniques for Determination of Volatile Organic Compounds in Air Samples[J].Trac Trends in Analytical Chemistry,2009,28(3):347-361.
[64] WANG B,SHAO M,LU S H,et al.Variation of Ambient Non-Methane Hydrocarbons in Beijing City in Summer 2008[J].Atmospheric Chemistry and Physics,2010,10(13):5565-5597.
[65] ALLWOODA J M,GOODACREA R.An Introduction to Liquid Chromatography-Mass Spectrometry Instrumentation Applied in Plant Metabolomic Analyses[J].Phytochemical Analysis,2010,21(1):33-47.
[66] PHILLIPS J B,BEENS J.Comprehensive Two-Dimensional Gas Chromatography:A Hyphenated Method With Strong Coupling Between the Two Dimensions[J].Journal of Chromatography A,1999,856(1/2):331-347.
[67] KALLIO M,HYÖTYLÄINEN T.Quantitative Aspects of Comprehensive Two-Dimensional Gas Chromatography[J].Journal of Chromatography A,2007,1148(2):228-235.
[68] MALEKNIA S D,BELL T L,ADAMS M A.PTR-MS Analysis of Reference and Plant-Emitted Volatile Organic Compounds[J].International Journal of Mass Spectrometry,2007,262(3):203-210.
[69] HIROSHI T,NOBUYUKI A,SATOSHI I,et al.Development of a PTR-TOFMS Instrument for Real-Time Measurements of Volatile Organic Compounds in Air[J].International Journal of Mass Spectrometry,2007,263(1):1-11.
[70] LACKNER M.Tunable Diode Laser Absorption Spectroscopy(TDLAS) in the Process Industries:A Review[J].Reviews in Chemical Engineering,2007,23(2):65-147.
[71] KETOLA R A,KIURU J T,TARKIAINEN V,et al.Detection of Volatile Organic Compounds by Temperature-Programmed Desorption Combined With Mass Spectrometry and Fourier Transform Infrared Spectroscopy[J].Analytical Chimica Acta,2006,562(2):245-251.
[72] CERCELARU C,IONEL I,VETRES I.Air Pollution Analysis Established by a DOAS System[J].Journal of Environmental Protection and Ecology,2014,15(2):395-404.
[73] PARK C,SCHADE G W,BOEDEKER I.Flux Measurements of Volatile Organic Compounds by the Relaxed Eddy Accumulation Method Combined With a GC-FID System in Urban Houston,Texas[J].Atmospheric Environment,2010,44(21/22):2605-2614.
[74] WANG M,ZENG L M,LU S H,et al.Development and Validation of A Cryogen-Free Automatic Gas Chromatograph System (GC-MS/FID) for Online Measurements of Volatile Organic Compounds[J].Analytical Methods,2014,6(23):9424-9434.
[75] CAVALCANTE R M,DE-ANDRADE M V F,MARINS R V,et al.Development of a Headspace-Gas Chromatography (HS-GC-PID-FID) Method for the Determination of VOCs in Environmental Aqueous Matrices:Optimization,Verification and Elimination of Matrix Effect and VOC Distribution on the Fortaleza Coast,Brazil[J].Microchemical Journal,2010,96(2):337-343.
[76] LI J,WU R R,LI Y Q,et al.Effects of Rigorous Emission Controls on Reducing Ambient Volatile Organic Compounds in Beijing,China[J].Science of the Total Environment,2016,557/558:531-541.
[77] WU R R,LI J,HAO Y F,et al.Evolution Process and Sources of Ambient Volatile Organic Compounds During a Severe Haze Event in Beijing,China[J].Science of the Total Environment,2016,560/561:62-72.
[78] 翟增秀,邹克华,李伟芳,等.天津中心城区环境空气挥发性有机物污染特征分析[J].环境科学,2013,34(12):4513-4518.[ZHAI Zeng-xiu,ZOU Ke-hua,LI Wei-fang,et al.Pollution Characterization of Volatile Organic Compounds in Ambient Air of Tianjin Downtown[J].Environmental Science,2013,34(12):4513-4518.]
[79] HAN M,LU X Q,ZHAO C S,et al.Characterization and Source Apportionment of Volatile Organic Compounds in Urban and Suburban Tianjin,China[J].Advances in Atmospheric Sciences,2015,32(3):439-444.
[80] 宁晓宇,刘博,王亘.天津市某重点居住区VOCs污染现状浅析[J].科技导报,2011,29(29):56-60.[NING Xiao-yu,LIU Bo,WANG Gen.Volatile Organic Compounds Pollution in a Key Residential Area of Tianjin[J].Science & Technology Review,2011,29(29):56-60.]
[81] SHI J W,DENG H,BAI Z P,et al.Emission and Profile Characteristic of Volatile Organic Compounds Emitted From Coke Production,Iron Smelt,Heating Station and Power Plant in Liaoning Province,China[J].Science of the Total Environment,2015,515/516:101-108.
[82] 孙云杰,陆建刚,赵欣,等.南京市典型交通区与背景区春季大气中VOCs的污染水平与日变化趋势[J].生态与农村环境学报,2015,31(2):151-157.[SUN Yun-jie,LU Jian-gang,ZHAO Xin,et al.Atmospheric VOCs Pollution Level and Its Diurnal Variation in Typical Urban Traffic Area and Background Area of Nanjing of China in Spring[J].Journal of Ecology and Rural Environment,2015,31(2):151-157.]
[83] 杨笑笑,汤莉莉,胡丙鑫,等.南京城区夏季大气VOCs的来源及对SOA的生成研究:以亚青和青奥期间为例[J].中国环境科学,2016,36(10):2896-2902.[YANG Xiao-xiao,TANG Li-li,HU Bing-xin,et al.Sources Apportionment of Volatile Organic Compounds VOCs in Summertime Nanjing and Their Potential Contribution to Secondary Organic Aerosols(SOA)[J].China Environmental Science,2016,36(10):2896-2902.]
[84] 安俊琳,朱彬,王红磊,等.南京北郊大气VOCs变化特征及来源解析[J].环境科学,2014,35(12):4454-4464.[AN Jun-lin,ZHU Bin,WANG Hong-lei,et al.Characteristics and Source Apportionment of Volatile Organic Compounds (VOCs) in the Northern Suburb of Nanjing[J].Environmental Science,2014,35(12):4454-4464.]
[85] 张露露,蒋卫兵,张元勋,等.上海市青浦区大气挥发性有机化合物的特征[J].中国环境科学,2015,35(12):3550-3561.[ZHANG Lu-lu,JIANG Wei-bing,ZHANG Yuan-xun,et al.The Characteristics of Ambient Volatile Organic Compounds (VOCs) in Qingpu Shanghai,China[J].China Environmental Science,2015,35(12):3550-3561.]
[86] 罗达通,高健,王淑兰,等.上海秋季大气挥发性有机物特征及污染物来源分析[J].中国环境科学,2015,35(4):987-994.[LUO Da-tong,GAO Jian,WANG Shu-lan,et al.Characteristics of Volatile Organic Compounds and Relative Pollutants Observed in Autumn Shanghai[J].China Environmental Science,2015,35(4):987-994.]
[87] 王红丽.上海市光化学污染期间挥发性有机物的组成特征及其对臭氧生成的影响研究[J].环境科学学报,2015,35(6):1603-1611.[WANG Hong-li.Characterization of Volatile Organic Compounds (VOCs) and the Impact on Ozone Formation During the Photochemical Smog Episode in Shanghai,China[J].Acta Scientiae Circumstantiae,2015,35(6):1603-1611.]
[88] ZOU Y,DENG X J,ZHU D,et al.Characteristics of 1 Year of Observational Data of VOCs,NOx and O₃ at a Suburban Site in Guangzhou,China[J].Atmospheric Chemistry and Physics,2015,15:6625-6636.
[89] 邹宇,邓雪娇,王伯光,等.广州番禺大气成分站挥发性有机物的污染特征[J].中国环境科学,2013,33(5):808-813.[ZOU Yu,DENG Xue-jiao,WANG Bo-guang,et al.Pollution Characteristics of Volatile Organic Compounds in Panyu Composition Station[J].China Environmental Science,2013,33(5):808-813.]
[90] LYU X P,CHEN N,GUO H,et al.Ambient Volatile Organic Compounds and Their Effect on Ozone Production in Wuhan,Central China[J].Science of the Total Environment,2016,541:200-209.
[91] 祁心,郝庆菊,吉东生,等.重庆市北碚城区大气中VOCs组成特征研究[J].环境科学,2014,35(9):3293-3301.[QI Xin,HAO Qing-ju,JI Dong-sheng,et al.Composition Characteristics of Atmospheric Volatile Organic Compounds in the Urban Area of Beibei District,Chongqing[J].Environmental Science,2014,35(9):3293-3301.]
[92] 翟崇治,刘芮伶,余家燕,等.重庆城区大气VOCs的浓度变化特征与臭氧生成潜势[J].环境影响评价,2013,35(6):45-49,53.[ZHAI Chong-zhi,LIU Rui-ling,YU Jia-yan,et al.Concentration Variation Characteristics and Ozone Generation Potential of Atmospheric VOCs in Chongqing Urban Area[J].Environmental Impact Assessment,2013,35(6):45-49,53.]