我国典型印染行业废水处理污泥污染特征研究

doi:10.19741/j.issn.1673-4831.2019.0912

摘要/Abstract

摘要： 印染污泥因具有产量大、污染物含量高、成分复杂等特点，导致的环境问题日益突出。笔者选取国内14家印染企业及4家印染废水集中处理厂为研究对象，调研了企业的产品种类、主要染料及污水处理工艺等情况，参照危险废物鉴别方法深入分析了印染污泥中有机污染物和重金属的污染特性和分布特点。结果表明，印染污泥中检出苯胺、苯酚和石油溶剂等有机污染物，锌、钡、砷、铬、镍5种重金属检出率较高，涤纶类印染企业污泥中金属锑的含量普遍高于其他类型企业。此外，废水处理过程中不正规净水剂的使用会对印染污泥中重金属含量造成显著影响。

关键词: 印染污泥, 污染特征, 重金属, 有机物

Abstract: With the development of textile printing and dyeing industry in China, dyeing sludge has caused increasingly serious environmental problems due to its multiple characteristics of large output, high pollutant content, complex composition, etc. 14 dyeing enterprises and 4 dyeing wastewater treatment plants were selected as research objects in the country. And then, product types, main dyes, wastewater treatment technology and others were investigated. Referring to the identification methods of hazardous waste, pollution and distribution characteristics of organic pollutants were analyzed deeply in dyeing sludge, as well as the heavy metals. The results show that organic pollutants such as aniline, phenol and petroleum solvents were detected in dyeing sludge; the detection rates of heavy metals such as Zn, Ba, As, Cr and Ni were also high; and the content of Sb was generally higher than that of other types of enterprises in polyester printing dyeing sludge. Besides, the use of irregular water treatment agents did have a significant impact on the content of heavy metals in dyeing sludge.

Key words: dyeing sludge, pollution characteristics, organic pollutants, heavy metal

中图分类号:

X323
X788

王玉婷, 赵泽华, 王逸, 华晶, 张大鹏, 张后虎, 焦少俊. 我国典型印染行业废水处理污泥污染特征研究[J]. 生态与农村环境学报, 2020, 36(12): 1598-1604.

ZHAO Ze-hua, WANG Yi, HUA Jing, ZHANG Da-peng, ZHANG Hou-hu, JIAO Shao-jun. Study on the Pollution Characteristics of Typical Textile Dyeing Sludge (TDS) in China[J]. Journal of Ecology and Rural Environment, 2020, 36(12): 1598-1604.

参考文献

[1] 王玉,徐勇军,方战强.印染污泥处理处置技术的研究进展[J].广东化工,2012,39(4):110-111.[WANG Yu,XU Yong-jun,FANG Zhan-qiang.Progress of the Textile Dyeing Sludge Treatmental and Disposal Techniques[J].Guangdong Chemical Industry,2012,39(4):110-111.]
[2] 环境保护部.2015年环境统计年报[Z].北京:环境保护部,2015:15-16.
[3] KANH S,SOKLUN H,YANG Z S,et al.Purification of Dye Wastewater Using Bicarbonate Activated Hydrogen Peroxide:Reaction Process and Mechanisms[J].Separation and Purification Technology,2020,232:115974.
[4] DE W J,YAO J C,WANG L,et al.Multivariate Optimization of the Pulse Electrochemical Oxidation for Treating Recalcitrant Dye Wastewater[J].Separation and Purification Technology,2020,230:115851-115858.
[5] RANC M,LIU Y,SIDDIQUI A R,et al.Pyrolysis of Textile Dyeing Sludge in Fluidized Bed:Analysis of Products,and Migration and Distribution of Heavy Metals[J].Journal of Cleaner Production,2019,241:118308-118317.
[6] 杨盼,卢路,王继保,等.基于主成分分析的Spearman秩相关系数法在长江干流水质分析中的应用[J].环境工程,2019,37(8):76-80.[YANG Pan,LU Lu,WANG Ji-bao,et al.Analysis of Water Quality Trend in the Main Stream of the Yangtze River Based on Principal Component Analysis[J].Environmental Engineering,2019,37(8):76-80.]
[7] 刘潇,薛莹,纪毓鹏,等.基于主成分分析法的黄河口及其邻近水域水质评价[J].中国环境科学,2015,35(10):3187-3192.[LIU Xiao,XUE Ying,JI Yu-peng,et al.An Assessment of Water Quality in the Yellow River Estuary and Its Adjacent Waters Based on Principal Component Analysis[J].China Environmental Science,2015,35(10):3187-3192.]
[8] 环境保护部.《纺织染整行业污染防治可行技术指南(试行)》(征求意见稿,2014)[Z].北京:环境保护部,2014.
[9] 高庆国.典型印染行业废水污染特征及处理工艺应用[J].河南科技,2016(17):134-136.[GAO Qing-guo.Typical Printing and Dyeing Industry Wastewater Pollution Characteristics and Treatment Technology Application[J].Journal of Henan Science and Technology,2016(17):134-136.]
[10] 张鹏.吸附法和MBR法对印染废水深度处理的研究[D].广州:华南理工大学,2009.[ZHANG Peng.Study on Advanced Treatment in Dyeing Wastewater by Adsorption and the MBR[D].Guangzhou:South China University of Technology,2009.]
[11] MISHRA G,TRIPATHY M.A Critical Review of the Treatments for Decolourization of Textile Effluent[J].Colourage,1993,40:35-38.
[12] 马春燕,谭书琼,奚旦立.印染废水处理原则及方法[J].印染,2010,36(16):30-32.[MA Chun-yan,TAN Shu-qiong,XI Dan-li.Principles and Methods of Dyeing and Finishing Wastewater Treatment[J].Dyeing & Finishing,2010,36(16):30-32.]
[13] 周雷云.金属络合交联染料的合成和应用[D].大连:大连理工大学,2009.[ZHOU Lei-yun.Synthesis and Application of Metal-complexed Crosslinking Dyes[D].Dalian:Dalian University of Technology,2009.]
[14] 陈金坤.太湖流域印染企业生存发展与水污染防治[J].染整技术,2013,35(9):7-12.[CHEN Jin-kun.Survival Development and Water Pollution Control of Dyeing and Printing Enterprises in Taihu Basin[J].Textile Dyeing and Finishing Journal,2013,35(9):7-12.]
[15] 姚琪,沈莉萍,江明月.印染污泥的危险特性[J].印染,2016,42(23):51-55.[YAO Qi,SHEN Li-ping,JIANG Ming-yue.Hazardous Characteristics of Dyeing Sludge[J].Dyeing & Finishing,2016,42(23):51-55.]
[16] 周剑波,宁寻安,刘敬勇,等.印染污泥固化及稳定化处理研究[J].环境工程学报,2011,5(2):457-461.[ZHOU Jian-bo,NING Xun-an,LIU Jing-yong,et al.Study on Solidification/Stabilization Treatment of Textile Dyeing Sludge[J].Chinese Journal of Environmental Engineering,2011,5(2):457-461.]
[17] 萧斌,王丽苹,杨先贵,等.聚酯催化剂的研究进展[J].化学试剂,2010,32(3):223-226.[XIAO Bin,WANG Li-ping,YANG Xian-gui,et al.Development of Research on Polyester Catalyst[J].Chemical Reagents,2010,32(3):223-226.]
[18] 陈溥,王志刚.纺织染整助剂实用手册[M].北京:化学工业出版社,2003:380-392.
[19] SUNDAR S,CHAKRAVARTY J.Antimony Toxicity[J].International Journal of Environmental Research and Public Health,2010,7(12):4267-4277.
[20] 曹振宇.中国近代合成染料生产及染色技术发展研究[D].上海:东华大学,2008.[CAO Zhen-yu.The Study on Development of Synthetic Dyes Producting and Dyeing Technology in Mondern Times in China[D].Shanghai:Donghua University,2008.]
[21] 李敏慧,王宁.印染废水处理污泥危险废物鉴别过程中有毒污染物的迁移转化及鉴别因子筛选[J].环境监控与预警,2017,9(5):10-12.[LI Min-hui,WANG Ning.Transport and Transformation of Toxic Pollutants and Selection of Discrimination Factor in the Process of Identification for Hazardous Wastes of Printing and Dyeing Wastewater Treatment Sludge[J].Environmental Monitoring and Forewarning,2017,9(5):10-12.]
[22] NING X N,LIANG J Y,LI R J,et al.Aromatic Amine Contents,Component Distributions and Risk Assessment in Sludge From 10 Textile-Dyeing Plants[J].Chemosphere,2015,134:367-373.
[23] 王靖宇,宁寻安,李锐敬,等.典型印染废水处理过程中芳香烃化合物的污染特征及污泥生态风险评价[J].环境化学,2015,34(6):1201-1208.[WANG Jing-yu,NING Xun-an,LI Rui-jing,et al.Pollution Characteristics of Aromatic Hydrocarbons and Ecological Risk Assessment of the Sludge in the Typical Textile Dyeing Wastewater Treatment Process[J].Environmental Chemistry,2015,34(6):1201-1208.]
[24] 喻学敏,张龙,刘伟京,等.印染废水处理过程中污染物及毒性分析[J].环境污染与防治,2009,31(6):26-29,33.[YU Xue-min,ZHANG Long,LIU Wei-jing,et al.Analysis of Pollutant and Toxicity of Textile Wastewater in Treatment Process[J].Environmental Pollution & Control,2009,31(6):26-29,33.]
[25] 国家安全生产监督管理总局.危险化学品目录(2017版)[Z].北京:国家安全生产监督管理总局,2017:8-113.
[26] NING X N,LIN M Q,SHEN L Z,et al.Levels,Composition Profiles and Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in Sludge From Ten Textile Dyeing Plants[J].Environmental Research,2014,132:112-118.
[27] HU Y J,LI G J,YAN M,et al.Investigation Into the Distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in Wastewater Sewage Sludge and Its Resulting Pyrolysis Bio-Oils[J].Science of the Total Environment,2014,473/474:459-464.
[28] 卢杰,宁寻安,梁洁莹,等.印染污泥对蚯蚓的毒性效应研究[J].环境科学学报,2018,38(9):3739-3745.[LU Jie,NING Xun-an,LIANG Jie-ying,et al.Study on the Toxicity Effect of Textile Dyeing Sludge on Earthworms[J].Acta Scientiae Circumstantiae,2018,38(9):3739-3745.]
[29] 李季,瞿庆玲.印染生产废水处理生化污泥固废属性鉴别研究[J].污染防治技术,2017,30(2):1-6.[LI Ji,QU Qing-ling.A Study on Solid Property of the Sewage Sludge From Printing and Dyeing Manufacturers[J].Pollution Control Technology,2017,30(2):1-6.]